Bis(dimethylformamide-2κO)dipyridine-1κN,3κN-bis(μ-2′-salicylbenzohydrazidato)-1κ3O,N,O′:2κ2N,O";2κ2N,O":3κ3O,N,O′-trinickel(II) dimethylformamide disolvate hemihydrate

被引：10

作者：

Yang, MX ^{[1
]}

Lin, S ^{[1
]}

机构：

[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fujian 350007, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805013875

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the trinuclear nickel(II) complex of the title compound, [Ni-3(C30H20N4O6)(2)(C5H5N)(2)(C2H6NO)(2)](.)2C(3)H(7)NO(.)0.5H(2)O, the central Ni2+ ion is located on an inversion centre. This Ni2+ ion has a distorted octahedral coordination geometry involving two N and two O atoms from the 2 '-salicylbenzohydrazidate ligands in the equatorial plane and two N atoms from two dimethylformamide molecules in the axial positions. The inversion-related outer Ni2+ ions, separated by 9.3038 (7) angstrom, have square-planar coordination environments.

引用

页码：M1095 / M1096

页数：2

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