Highly dispersed oleic-induced nanometric C@Na3V2(PO4)2F3 composites for efficient Na-ion batteries

被引:34
作者
Criado, A. [1 ]
Lavela, P. [1 ]
Ortiz, G. [1 ]
Tirado, J. L. [1 ]
Perez-Vicente, C. [1 ]
Bahrou, N. [2 ]
Edfouf, Z. [2 ]
机构
[1] Univ Cordoba, Inst Univ Quim Fina & Nanoquim, Dept Quim Inorgan & Ingn Quim, Edificio Marie Curie,Campus Rabanales, C ordoba 14071, Spain
[2] Univ Mohammed 5, Fac Sci, Mat & Nanomat Photovolta Convers & Electrochem St, 4 Av Ibn Battota BP 1014, Rabat, Morocco
关键词
Sodium-ion batteries; Intercalation reactions; Oleic; Na3V2(PO4)(2)F-3; CATHODE MATERIAL; LITHIUM-ION; ELECTROCHEMICAL PROPERTIES; NA3V2(PO4)(2)F-3 CATHODE; ENERGY-STORAGE; HIGH-POWER; SODIUM;
D O I
10.1016/j.electacta.2019.135502
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
C@Na3V2(PO4)(2)F-3 samples were synthesized by an emulsion method using oleic acid as a surfactant and Vaseline oil as organic media of the micellar system. Their structural, chemical and morphological properties are determined by at the light of solid-state techniques, including X-ray diffraction, electron microscopy, and Raman and XPS spectroscopies. Electrochemical tests, performed by the galvanostatic method, show that the use of oleic acid as a surfactant improves the electrode kinetic properties and consequently the electrochemical behavior as a cathode for sodium-ion batteries. (C) 2019 Elsevier Ltd. All rights reserved.
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页数:8
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