Experimental analysis of membrane and pressure swing adsorption (PSA) for the hydrogen separation from natural gas

被引：104

作者：

Liemberger, Werner ^{[1
]}

Gross, Markus ^{[1
]}

Miltner, Martin ^{[1
]}

Harasek, Michael ^{[1
]}

机构：

[1] TU Wien, Inst Chem Engn, Getreidemarkt 9-166, A-1060 Vienna, Austria

来源：

JOURNAL OF CLEANER PRODUCTION | 2017年 / 167卷

关键词：

Hydrogen transportation; Natural gas grid infrastructure; Fuel-cell quality hydrogen; Membrane separation; Pressure swing adsorption; Power-to-gas; ENERGY-STORAGE TECHNOLOGIES; MOLECULAR-SIEVE MEMBRANES; POLYMERIC MEMBRANES; POLYIMIDE MEMBRANES; FUEL-CELL; PURIFICATION; CARBON; MIXTURES; RECOVERY; ELECTROLYSIS;

D O I：

10.1016/j.jclepro.2017.08.012

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The current work presents a process that separates hydrogen from mixtures with natural gas transported in the natural gas grid. The aim is to achieve hydrogen at fuel cell quality (99.97% (v/v) according to ISO 14687-2:2012). Due to gas grid regulations in Austria the hydrogen content is limited to a maximum of 4% (v/v). In a hybrid approach based on membrane separation and pressure swing adsorption (PSA) the supplied high pressure hydrogen natural gas mixture (up to 120 bar) is pre-enriched by membrane technology and further upgraded to the required quality by PSA. The majority of the feed gas is kept at grid pressure, which ensures a high energetic efficiency. The remaining components, separated by PSA, are re-compressed and returned to the grid. Beside the technological feasibility, the influence of various process parameters (e.g. stage-cut, permeate conditions, PSA hydrogen recovery) is analysed. Based on the results, the required amount of energy of 0.8-1.5 kWh/m(3) (fuel-cell quality hydrogen at 25.81 bar(a)) is calculated for the so called HylyPure (R) process. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：896 / 907

页数：12

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