Oxidative dehydrogenation of ethane and propane: How far from commercial implementation?

被引：851
|
作者：
Cavani, F. [1 ]
Ballarini, N. [1 ]
Cericola, A. [1 ]
机构：
[1] Alma Mater Studiorum Univ Bologna, Dipartimento Chim Ind & Mat, I-40136 Bologna, Italy
来源：
CATALYSIS TODAY | 2007年 / 127卷 / 1-4期
关键词：
oxidative dehydrogenation; olefins production; propane; ethane; reactor configurations;
D O I：
10.1016/j.cattod.2007.05.009
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
This review examines the recent literature on the oxidative dehydrogenation (ODH) of ethane and propane, which aims for the synthesis of the corresponding alkenes. The following aspects are discussed: (a) the main features affecting the catalytic properties of systems based on supported vanadium oxide and molybdenum oxide; (b) the characteristics of catalysts producing outstanding olefin yields; (c) advantages in selectivity gained by means of either special reactor configurations or non-conventional conduction of the reaction; (d) the contribution of homogeneous reactions to the formation of olefins during the oxidation of alkanes. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：113 / 131
页数：19
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