Counteranion-directed assembly of zinc(II) coordination polymers with 1,3,5-tris(1-imidazolyl)benzene

被引：20

作者：

Su, Zhi ^{[1
]}

Wang, Zhi-Bin ^{[1
]}

Sun, Wei-Yin ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 11期

基金：

中国国家自然科学基金;

关键词：

Znic(II) coordination polymers; Counteranion-directed assembly; gra topology; Photoluminescence; CRYSTAL; LIGANDS; FRAMEWORKS; NETWORKS; PHOTOLUMINESCENCE; CADMIUM(II); COMPLEXES;

D O I：

10.1016/j.inoche.2010.07.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel coordination polymers [Zn-2(tib)(chda)Cl-2] (1) and [Zn(tib)I]I (2) have been prepared by reactions of 1,3,5-tris(1-imidazolyl)benzene (tib) and 1,2-cyclohexanedicarboxylic acid (H(2)chda) with corresponding Zn(II) salts, respectively. Complex 1 has a three-dimensional (3D) structure with rare gra (graphite) topology, while 2 is a typical two-dimensional (2D) (4.8(2)) network. The results revealed that the counteranion plays a subtle and important role in the assembly procedure. Photoluminescent property of the complexes was investigated. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1278 / 1280

页数：3

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