Counteranion-directed assembly of zinc(II) coordination polymers with 1,3,5-tris(1-imidazolyl)benzene

被引：20
|
作者：
Su, Zhi [1 ]
Wang, Zhi-Bin [1 ]
Sun, Wei-Yin [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 11期
基金：
中国国家自然科学基金;
关键词：
Znic(II) coordination polymers; Counteranion-directed assembly; gra topology; Photoluminescence; CRYSTAL; LIGANDS; FRAMEWORKS; NETWORKS; PHOTOLUMINESCENCE; CADMIUM(II); COMPLEXES;
D O I：
10.1016/j.inoche.2010.07.015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel coordination polymers [Zn-2(tib)(chda)Cl-2] (1) and [Zn(tib)I]I (2) have been prepared by reactions of 1,3,5-tris(1-imidazolyl)benzene (tib) and 1,2-cyclohexanedicarboxylic acid (H(2)chda) with corresponding Zn(II) salts, respectively. Complex 1 has a three-dimensional (3D) structure with rare gra (graphite) topology, while 2 is a typical two-dimensional (2D) (4.8(2)) network. The results revealed that the counteranion plays a subtle and important role in the assembly procedure. Photoluminescent property of the complexes was investigated. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：1278 / 1280
页数：3
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