Effect of lanthanide contraction on crystal structures of lanthanide coordination polymers with 2,5-piperazinedione-1,4-diacetic acid

被引:49
作者
Zhuang, Gui-Lin
Kong, Xiang-Jian [1 ]
Long, La-Sheng
Huang, Rong-Bin
Zheng, Lan-Sun
机构
[1] Xiamen Univ, State Key Lab Phys Chem Solid Surface, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
来源
CRYSTENGCOMM | 2010年 / 12卷 / 10期
关键词
METAL-ORGANIC FRAMEWORK; MAGNETIC-PROPERTIES; COMPLEXES; LUMINESCENT; DIVERSITY; CHEMISTRY; SERIES; IONS;
D O I
10.1039/c001537g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of lanthanide coordination polymers have been synthesized through the hydrothermal reaction of 2,5-piperazinedione-1,4-diacetic acid (H2PODC) and Ln(NO3)(3) (Ln = La, 1; Pr, 2; Sm, 3; Ho, 4 and Er, 5). Crystal structure analysis reveals that their structural variations are attributed to the effect of lanthanide contraction.
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页码:2691 / 2694
页数:4
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