Methane conversion to hydrogen and higher hydrocarbons by double pulsed glow discharge

被引:29
作者
Ghorbanzadeh, AA
Matin, NS
机构
[1] Sharif Univ Technol, Dept Phys, Tehran, Iran
[2] Res Inst Petr Ind, Tehran, Iran
关键词
glow discharge; methane conversion; nonequilibrium plasma; acetylene; ethylene; hydrogen;
D O I
10.1007/s11090-004-8832-7
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Pulsed atmospheric glow plasma, sustained by corona discharge, was utilized to convert methane. Analysis by gas chromatography showed that hydrogen and C-2-products are the main constituents of outlet mixture while C2+-products with small concentrations were also detected. The chemical energy efficiency turned out to be about 9% for the best result obtained by this type of reactor. It has been shown that more improvement of energy efficiency is possible by increasing the pulse repetition rate.
引用
收藏
页码:19 / 29
页数:11
相关论文
共 34 条
[1]   Ozone generation by silent electric discharge and its application in tertiary treatment of tannery effluent [J].
Balakrishnan, PA ;
Arunagiri, A ;
Rao, PG .
JOURNAL OF ELECTROSTATICS, 2002, 56 (01) :77-86
[2]   Plasma catalytic reforming of methane [J].
Bromberg, L ;
Cohn, DR ;
Rabinovich, A ;
Alexeev, N .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1999, 24 (12) :1131-1137
[3]  
Chang JS, 2001, SCI TECHNOL ADV MAT, V2
[4]   CORONA DISCHARGE PROCESSES [J].
CHANG, JS ;
LAWLESS, PA ;
YAMAMOTO, T .
IEEE TRANSACTIONS ON PLASMA SCIENCE, 1991, 19 (06) :1152-1166
[5]   Syngas production via methane steam reforming with oxygen: plasma reactors versus chemical reactors [J].
Cormier, JM ;
Rusu, I .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2001, 34 (18) :2798-2803
[6]   EFFICIENT DESIGN OF MULTISTAGE MAGNETIC PULSE-COMPRESSION [J].
DEGUCHI, H ;
HATAKEYAMA, T ;
MURATA, E ;
IZAWA, Y ;
YAMANAKA, C .
IEEE JOURNAL OF QUANTUM ELECTRONICS, 1994, 30 (12) :2934-2938
[7]   Operational experience of a commercial scale plant of electron beam purification of flue gas [J].
Doi, Y ;
Nakanishi, I ;
Konno, Y .
RADIATION PHYSICS AND CHEMISTRY, 2000, 57 (3-6) :495-499
[8]   NONEQUILIBRIUM VOLUME PLASMA CHEMICAL-PROCESSING [J].
ELIASSON, B ;
KOGELSCHATZ, U .
IEEE TRANSACTIONS ON PLASMA SCIENCE, 1991, 19 (06) :1063-1077
[9]   OZONE SYNTHESIS FROM OXYGEN IN DIELECTRIC BARRIER DISCHARGES [J].
ELIASSON, B ;
HIRTH, M ;
KOGELSCHATZ, U .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1987, 20 (11) :1421-1437
[10]  
FEY MG, 1979, 88 AICHE NAT M PHIL