Synthesis of Ramirez ylides from Morita-Baylis-Hillman adducts of α-bromocinnamaldehyde: an intramolecular 1,6-conjugate addition of phosphorus ylide

被引：8
作者：
Kim, Ko Hoon [1 ,2 ]
Lee, Sangku [3 ]
Lee, Junseong [1 ,2 ]
Kim, Jae Nyoung [1 ,2 ]
机构：
[1] Chonnam Natl Univ, Dept Chem, Kwangju 500757, South Korea
[2] Chonnam Natl Univ, Inst Basic Sci, Kwangju 500757, South Korea
[3] Korea Res Inst Biosci & Biotechnol, Targeted Med Res Ctr, Cheongwon 363883, Chungbuk, South Korea
来源：
TETRAHEDRON LETTERS | 2015年 / 56卷 / 29期
基金：
新加坡国家研究基金会;
关键词：
Ramirez ylides; Morita-Baylis-Hillman adducts; Phosphines; Intramolecular 1,6-conjugate addition; EFFICIENT SYNTHESIS; WITTIG OLEFINATION; ASSISTED SYNTHESIS; PHOSPHINE; COMPLEXES; 1-C9H6PMEPH2; CONSTRUCTION; 1,6-ADDITION; CYCLIZATION; CARBONATES;
D O I：
10.1016/j.tetlet.2015.05.083
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Ramirez ylides were synthesized in good yields from Morita-Baylis-Hillman acetates of alpha-bromocin-namaldehyde and phosphines in a one-pot reaction. The Ramirez ylides were formed by a novel intramolecular 1,6-conjugate addition of phosphorus ylide as a key step. (c) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4349 / 4353
页数：5
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