Bulk production of quasi-aligned carbon nanotube bundles by the catalytic chemical vapour deposition (CCVD) method

被引:167
作者
Mukhopadhyay, K
Koshio, A
Sugai, T
Tanaka, N
Shinohara, H [1 ]
Konya, Z
Nagy, JB
机构
[1] Nagoya Univ, Fac Sci, Dept Chem, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Fac Engn, Dept Appl Phys, Nagoya, Aichi 4648603, Japan
[3] Fac Univ Notre Dame Paix, Lab Resonance Magnet Nucl, B-5000 Namur, Belgium
基金
日本学术振兴会;
关键词
D O I
10.1016/S0009-2614(99)00202-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The large-scale production of quasi-aligned carbon nanotube bundles is reported. The method includes catalytic decomposition of acetylene over well-dispersed metal particles embedded in commercially available zeolite at a lower temperature (700 degrees C). In-depth studies of this nanotube through scanning electron microscopy and transmission electron microscopy reveal their homogeneity as well as perfect graphitization, along with inner (2.5-4 nm) and outer diameters (10-12 nm) of the tubes. Details of the optimum conditions for producing these nanotubes are also described. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:117 / 124
页数:8
相关论文
共 14 条
[1]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[2]   Laser-assisted production of multi-walled carbon nanotubes from acetylene [J].
Kanzow, H ;
Schmalz, A ;
Ding, A .
CHEMICAL PHYSICS LETTERS, 1998, 295 (5-6) :525-530
[3]   Synthesis of individual single-walled carbon nanotubes on patterned silicon wafers [J].
Kong, J ;
Soh, HT ;
Cassell, AM ;
Quate, CF ;
Dai, HJ .
NATURE, 1998, 395 (6705) :878-881
[4]   Carbon nanotubes of polyethylene [J].
Kukovitskii, EF ;
Chernozatonskii, LA ;
Lvov, SG ;
Melnik, NN .
CHEMICAL PHYSICS LETTERS, 1997, 266 (3-4) :323-328
[5]   Large-scale synthesis of aligned carbon nanotubes [J].
Li, WZ ;
Xie, SS ;
Qian, LX ;
Chang, BH ;
Zou, BS ;
Zhou, WY ;
Zhao, RA ;
Wang, G .
SCIENCE, 1996, 274 (5293) :1701-1703
[6]   A simple and novel way to synthesize aligned nanotube bundles at low temperature [J].
Mukhopadhyay, K ;
Koshio, A ;
Tanaka, N ;
Shinohara, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1998, 37 (10B) :L1257-L1259
[7]   Growing carbon nanotubes by microwave plasma-enhanced chemical vapor deposition [J].
Qin, LC ;
Zhou, D ;
Krauss, AR ;
Gruen, DM .
APPLIED PHYSICS LETTERS, 1998, 72 (26) :3437-3439
[8]  
Rao C.N.R., 1998, J CHEM SOC CHEM COMM, V15, P1525
[9]   Synthesis of large arrays of well-aligned carbon nanotubes on glass [J].
Ren, ZF ;
Huang, ZP ;
Xu, JW ;
Wang, JH ;
Bush, P ;
Siegal, MP ;
Provencio, PN .
SCIENCE, 1998, 282 (5391) :1105-1107
[10]   Conical beams from open nanotubes [J].
Saito, Y ;
Hamaguchi, K ;
Hata, K ;
Uchida, K ;
Tasaka, Y ;
Ikazaki, F ;
Yumura, M ;
Kasuya, A ;
Nishina, Y .
NATURE, 1997, 389 (6651) :554-555