A new SiO/C anode composition for lithium-ion battery

被引：116

作者：

Doh, Chil-Hoon ^{[1
]}

Park, Chul-Wan ^{[2
]}

Shin, Hye-Min ^{[1
]}

Kim, Dong-Hun ^{[1
]}

Chung, Young-Dong ^{[1
]}

Moon, Seong-In ^{[1
]}

Jin, Bong-Soo ^{[1
]}

Kim, Hyun-Soo ^{[1
]}

Veluchamy, Angathevar ^{[1
,3
]}

机构：

[1] Korea Electrotechnol Res Inst, Chang Won 641120, South Korea

[2] SODIFF New Mat, Youngju 750080, South Korea

[3] Cent Electrochem Res Inst, Karaikkudi 630006, Tamil Nadu, India

来源：

JOURNAL OF POWER SOURCES | 2008年 / 179卷 / 01期

关键词：

high energy ball milling; SiO/graphite composite; anode; li-ion battery;

D O I：

10.1016/j.jpowsour.2007.12.074

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new anode composition comprising SiO and graphite(C) is prepared through a high-energy ball milling process. During the first cycle, the anode delivers high discharge and charge capacity values of 1556 and 693 mAh g(-1), respectively. The electrode shows a reversible charge capacity value of 688 mAh g(-1) at the 30th cycle with 99% Coulombic efficiency. X-ray diffraction analysis reveals that ball milling does not produce any new compound, but only causes a reduction in particle size. The irreversible and reversible capacities appear to be interdependent. (C) 2008 Published by Elsevier B.V.

引用

页码：367 / 370

页数：4

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