XANES MnK edge in NaNbO3 based ceramics doped with Mn and Bi ions

被引:0
作者
Wolska, A. [1 ,2 ]
Molak, A. [3 ]
Lawniczak-Jablonska, K. [2 ]
Kachniarz, J. [2 ]
Piskorska, E. [2 ]
Demchenko, I. [2 ]
Gruszka, I. [3 ]
Lindle, D. W. [1 ]
机构
[1] Univ Nevada, Dept Chem, Las Vegas, NV 89154 USA
[2] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
[3] Univ Silesia, Inst Phys, PL-40007 Katowice, Poland
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O4 [物理学];
学科分类号
0702 ;
摘要
Sodium niobate based ceramics doped with Mn atoms have been sintered from oxides. The Bi co-dopants were introduced to increase the solubility limit for Mn atoms. Two series of samples were heated at lowered air pressure to produce oxygen nonstoichiometry. X-ray Absorption Near Edge Structure (XANES) spectra at Mn K-edge were measured for samples with and without Bi co-dopants. Theoretical XANES spectra were calculated using the Real Space Multiple Scattering method (FEFF 8 code). The simulation showed that ceramics samples have Pbcm symmetry and all of them have Mn atoms located in a Nb sublattice.
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页码:989 / 991
页数:3
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