Syntheses and properties of thiophene-inserted [3]dendralenes with redox-active 1,3-dithiol-2-ylidene units

被引：11

作者：

Hasegawa, Masashi ^{[1
]}

Fujioka, Atsushi ^{[1
]}

Kubo, Takashi ^{[1
]}

Honda, Tomohito ^{[1
]}

Miyamoto, Hisakazu ^{[1
,2
]}

Misaki, Yohji ^{[1
,2
]}

机构：

[1] Ehime Univ, Dept Appl Chem, Grad Sch Engn, Matsuyama, Ehime 7908577, Japan

[2] JST, CREST, Matsuyama, Ehime 7908577, Japan

来源：

CHEMISTRY LETTERS | 2008年 / 37卷 / 04期

关键词：

D O I：

10.1246/cl.2008.474

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel dendralene type cross-conjugate molecules based on 1,3-dithiol-2-ylidene units with thiophene have been prepared. The conjugation in the oxidized stage is mainly through the thiophene core, while the cross-conjugated nature is observed in the neutral state. The CT complex of 2a with TCNQF(4) shows moderated electrical conductivity of 10(-4) S cm(-1).

引用

页码：474 / 475

页数：2

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