Synthesis and transformation of a novel methano[60]fullerene having a formyl group

被引：23
作者：
Hamada, M [1 ]
Hino, T [1 ]
Kinbara, K [1 ]
Saigo, K [1 ]
机构：
[1] Univ Tokyo, Grad Sch Frontier Sci, Dept Integrated Biosci, Bunkyo Ku, Hongo, Tokyo 1138656, Japan
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 30期
基金：
日本学术振兴会;
关键词：
D O I：
10.1016/S0040-4039(01)00944-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of [60]fullerene with a dimethylsulfonium alpha -formylalkylide gave a novel methano[60]fullerene having a formyl group at the bridge-head carbon, This 2.2-[60]fulleroalkanal was readily converted into a variety of N-aryl-2,2-[60]fulleroaldimines by condensation with aromatic amines: one of them showed efficient quenching of the fluorescence of the [60]fullerene core, due to a photoinduced intramolecular electron transfer. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：5069 / 5071
页数：3
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