Dielectric study of the liquid crystalline dimer α,ω-bis(4′-cyanobiphenyl-4-yloxy)decane

The dielectric properties of a nematogenic dimer alpha,omega-bis(4'-cyanobiphenyl-4-yloxy)decane in the nematic and isotropic phases have been investigated in the frequency range between 100 Hz and 13 MHz. It was found that the compound is characterized by a positive dielectric anisotropy. The dielectric constant in the nematic phase is lower than that in the isotropic phase, which suggests variation in the conformational distribution of the dimer after the phase transition. Only one relaxation process, both in the nematic and isotropic phases, has been observed in the frequency range used: the relaxation frequency has been found to take values between 2 and 4 MHz, depending on the temperature.