The influence of temperature on the heat effects of acid-base interaction in aqueous solutions of citric acid

被引:0
|
作者
Kochergina, L. A. [1 ]
Vasil'ev, V. P. [1 ]
Krutov, D. V. [1 ]
Krutova, O. N. [1 ]
机构
[1] Ivanovo State Univ Chem Technol, Ivanovo, Russia
关键词
D O I
10.1007/s11504-008-4010-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The heat effects of interaction of a solution of citric acid with solutions of HNO3 and KOH at 288.15, 298.15, and 308.15 K and ionic strength values 0.5, 1.0, and 1.5 (KNO3) were measured calorimetrically. The heat effects of acid dissociation were calculated using the HEAT program. The standard thermodynamic characteristics of step dissociation of citric acid were determined.
引用
收藏
页码:565 / 570
页数:6
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