Biosensor-based real-time monitoring of paracetamol photocatalytic degradation

被引:15
作者
Calas-Blanchard, Carole [1 ]
Istamboulie, Georges [1 ]
Bontoux, Margot [1 ]
Plantard, Gael [2 ]
Goetz, Vincent [2 ]
Noguer, Thierry [1 ]
机构
[1] Univ Perpignan, F-66860 Perpignan, France
[2] Natl Ctr Sci Res, UPR 8521, Lab Proc Mat & Solar Energy, Tecnosud,Rambla Thermodynam, F-66100 Perpignan, France
关键词
Tyrosinase; Biosensor; Paracetamol; Photocatalysis; Depollution monitoring; AQUEOUS-SOLUTIONS; WATER-TREATMENT; OXIDATION; ACETAMINOPHEN; TYROSINASE; AVOCADO; PEDOT;
D O I
10.1016/j.chemosphere.2015.03.019
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This paper presents for the first time the integration of a biosensor for the on-line, real-time monitoring of a photocatalytic degradation process. Paracetamol was used as a model molecule due to its wide use and occurrence in environmental waters. The biosensor was developed based on tyrosinase immobilization in a polyvinylalcohol photocrosslinkable polymer. It was inserted in a computer-controlled flow system installed besides a photocatalytic reactor including titanium dioxide (TiO2) as photocatalyst. It was shown that the biosensor was able to accurately monitor the paracetamol degradation with time. Compared with conventional HPLC analysis, the described device provides a real-time information on the reaction advancement, allowing a better control of the photodegradation process. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:124 / 129
页数:6
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