The adsorption of and reaction of NO2 on Ag(111)-p(4 x 4)-O and formation of surface nitrate

被引：19

作者：

Alemozafar, AR ^{[1
]}

Madix, RJ ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA

来源：

SURFACE SCIENCE | 2005年 / 587卷 / 03期

基金：

美国国家科学基金会;

关键词：

scanning tunneling microscopy; thermal desorption spectroscopy; surface chemical reaction; silver; inorganic compounds; oxygen; nitrogen dioxide; single crystal surfaces;

D O I：

10.1016/j.susc.2005.05.019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption and reaction of nitrogen dioxide on the Ag(1 1 1)-p(4 x 4)-O surface has been investigated with RAIRS, TPRS and STM. At 300 K NO2 initially reacts with the oxygen overlayer to form nitrate in p(3 x 3) and p(4 x 4) structures, which convert to a new p(3 x 3) at saturation coverage. Surface pitting during nitrate adsorption is suggestive of the incorporation of silver atoms into the NO3 structure. With heating NO3 decomposes into NO2 and O at 396 K and 497 K, and oxygen desorbs at 578 K. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：193 / 204

页数：12

共 32 条

[1] CO-induced segregation of hydrogen into the subsurface on Ni(110) [J].

Alemozafar, AR ;

Madix, RJ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (22) :7247-7252

[2] Two-dimensional condensation anisotropic crystallization:: H2/Ni(110) [J].

Alemozafar, AR ;

Madix, RJ .

SURFACE SCIENCE, 2004, 557 (1-3) :231-242

[3] Topographic nano-restructuring: sulfur dioxide adsorption on Cu(110) [J].

Alemozafar, AR ;

Guo, XC ;

Madix, RJ .

SURFACE SCIENCE, 2003, 524 (1-3) :L84-L88

[4] Reaction of sulfur dioxide with Ag(110)-p(2 x 1)-O: a LEED, TPRS, and STM investigation [J].

Alemozafar, AR ;

Guo, XC ;

Madix, RJ ;

Hartmann, N ;

Wang, J .

SURFACE SCIENCE, 2002, 504 (1-3) :223-234

[5] Adsorption and reaction of sulfur dioxide with Cu(110) and Cu(110)-p(2x1)-O [J].

Alemozafar, AR ;

Guo, XC ;

Madix, RJ .

JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (11) :4698-4706

[6]

ALEMOZAFAR AR, IN PRESS J PHYS CHEM

[7]

ALEMOZAFAR AR, IN PRESS SURF SCI

[8]

ALEMOZAFAR AR, UNPUB

[9] GENERATION OF ATOMIC OXYGEN ON AG(111) AND AG(110) USING NO2 - A TPD, LEED, HREELS, XPS AND NRA STUDY [J].

BARE, SR ;

GRIFFITHS, K ;

LENNARD, WN ;

TANG, HT .

SURFACE SCIENCE, 1995, 342 (1-3) :185-198

[10] OXYGEN-CHEMISORPTION ON METAL-SURFACES - GENERAL TRENDS FOR CU, NI AND AG [J].

BESENBACHER, F ;

NORSKOV, JK .

PROGRESS IN SURFACE SCIENCE, 1993, 44 (01) :5-66

← 1 2 3 4 →