High-spin carbonyl complexes of iron(i) and cobalt(i)

被引：10

作者：

Schneider, Christian ^{[1
]}

Guggotz, Lukas ^{[1
]}

Werncke, C. Gunnar ^{[1
]}

机构：

[1] Philipps Univ Marburg, Chem Dept, Hans Meerwein Str 4, D-35032 Marburg, Germany

来源：

DALTON TRANSACTIONS | 2021年 / 51卷 / 01期

关键词：

AUXILIARY BASIS-SETS; ENERGY; BOND; APPROXIMATION; MONOXIDE; BINDING; CO;

D O I：

10.1039/d1dt03924e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal carbonyl complexes are almost exclusively found in a low-spin state due to the strong-field nature of the CO ligand. Here the characterisation of highly labile three-coordinate metal(i) monocarbonyl complexes of iron and cobalt is presented. Experimental and quantum chemical examinations reveal their high-spin configuration.

引用

页码：179 / 184

页数：6

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