High-spin carbonyl complexes of iron(i) and cobalt(i)

被引：10

作者：

Schneider, Christian ^{[1
]}

Guggotz, Lukas ^{[1
]}

Werncke, C. Gunnar ^{[1
]}

机构：

[1] Philipps Univ Marburg, Chem Dept, Hans Meerwein Str 4, D-35032 Marburg, Germany

来源：

DALTON TRANSACTIONS | 2021年 / 51卷 / 01期

关键词：

AUXILIARY BASIS-SETS; ENERGY; BOND; APPROXIMATION; MONOXIDE; BINDING; CO;

D O I：

10.1039/d1dt03924e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal carbonyl complexes are almost exclusively found in a low-spin state due to the strong-field nature of the CO ligand. Here the characterisation of highly labile three-coordinate metal(i) monocarbonyl complexes of iron and cobalt is presented. Experimental and quantum chemical examinations reveal their high-spin configuration.

引用

页码：179 / 184

页数：6

共 50 条

[21] Synthesis of N-heterocyclic carbene rhenium(I) carbonyl complexes [J].

Chen, Chang-Hung ;

Liu, Yi-Hung ;

Peng, Shie-Ming ;

Chen, Jwu-Ting ;

Liu, Shiuh-Tzung .

DALTON TRANSACTIONS, 2012, 41 (09) :2747-2754

[22] Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide Ligand [J].

Hicks, Jamie ;

Jones, Cameron .

ORGANOMETALLICS, 2015, 34 (11) :2118-2121

[23] Isolation and Characterization of Stable Iron(I) Sulfide Complexes [J].

Rodriguez, Meghan M. ;

Stubbert, Bryan D. ;

Scarborough, Christopher C. ;

Brennessel, William W. ;

Bill, Eckhard ;

Holland, Patrick L. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (33) :8247-8250

[24] Nickelacyclopentadienylchromium Tricarbonyl Unit as a Bulky Pseudohalogen in Cyclopentadienylchromium Complexes Leading to Low-Energy High-Spin Structures [J].

Zeng, Yi ;

Yu, Ying ;

Feng, Hao ;

King, R. Bruce ;

Schaefer, Henry F., III .

INORGANIC CHEMISTRY, 2015, 54 (11) :5309-5315

[25] Tetrafluoroethylene versus trifluoromethylfluorocarbene complexes of cobalt carbonyl [J].

He, Jialuo ;

Li, Guoliang ;

Li, Qian-shu ;

Xie, Yaoming ;

King, R. Bruce .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 811 :91-97

[26] Synthesis and Reactivity of Cobalt(I) and Iridium(I) Complexes Bearing a Pentadentate N-Homoallyl-Substituted Bis(NHC) Pincer Ligand [J].

Tian, Yingying ;

Maulbetsch, Theo ;

Jordan, Ronja ;

Tornroos, Karl W. ;

Kunz, Doris .

ORGANOMETALLICS, 2020, 39 (08) :1221-1229

[27] Efficient Electronic Structure to Stabilize N2-Bridged Dinuclear Complexes Intended for N2 Activation: Iminophosphorane Iron(I) and Cobalt(I) [J].

Wasada-Tsutsui, Yuko ;

Wasada, Hiroaki ;

Suzuki, Tatsuya ;

Katayama, Akira ;

Kajita, Yuji ;

Inomata, Tomohiko ;

Ozawa, Tomohiro ;

Masuda, Hideki .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 2020 (15-16) :1411-1417

[28] Binuclear Pentalene Iron Carbonyl Complexes [J].

Li, Huidong ;

Feng, Hao ;

Sun, Weiguo ;

Xie, Yaoming ;

King, R. Bruce ;

Schaefer, Henry F., III .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (17) :2746-2755

[29] Magnetic and spectroscopic characterizations of high-spin cobalt(II) complex with soft-scorpionate ligand [J].

Baba, Haruyuki ;

Nakano, Motohiro .

INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 17 :177-179

[30] Methylborabenzene ligands in binuclear iron carbonyl derivatives: High spin states and iron-iron multiple bonding [J].

Chen, Jianlin ;

Chen, Shaoling ;

Liu, Zhiguo ;

Feng, Hao ;

Xie, Yaoming ;

King, R. Bruce .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 747 :106-112

← 1 2 3 4 5 →