Micro-nano structure hard carbon as a high performance anode material for sodium-ion batteries

被引:68
作者
Zheng, Peng [1 ]
Liu, Ting [1 ]
Guo, Shouwu [1 ,2 ]
机构
[1] Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Xian 710021, Shaanxi, Peoples R China
[2] Shanghai Jiao Tong Univ, Sch Elect Informat & Elect Engn, Dept Elect Engn, Shanghai 200240, Peoples R China
关键词
REDUCED GRAPHENE OXIDE; ULTRALONG CYCLE LIFE; LITHIUM-ION; ELECTRODE MATERIALS; CAPACITY; STORAGE; CELLULOSE; MICROSPHERES; SURFACE; NANOPARTICLES;
D O I
10.1038/srep35620
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Superior first-cycle Coulomb efficiency (above 80%) is displayed by filter paper-derived micro-nano structure hard carbon, and it delivers a high reversible capacity of 286 mAh g(-1) after 100 cycles as the anode for Na-ion battery at 20 mA g(-1). These advantageous performance characteristics are attributed to the unique micro-nano structure, which reduced the first irreversible capacity loss by limiting the contact between the electrode and electrolyte, and enhanced the capacity by accelerating electron and Na-ion transfer through inter-connected nano-particles and nano-pores, respectively. The good electrochemical performance indicates that this low-cost hard carbon could be a promising anode for Na-ion batteries.
引用
收藏
页数:7
相关论文
共 53 条
[1]   Hard Carbon and Carbon Nanotube Composites for the Improvement of Low-Voltage Performance in Na Ion Batteries [J].
Babu, R. Suresh ;
Pyo, Myoungho .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2014, 161 (06) :A1045-A1050
[2]   New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon [J].
Bommier, Clement ;
Surta, Todd Wesley ;
Dolgos, Michelle ;
Ji, Xiulei .
NANO LETTERS, 2015, 15 (09) :5888-5892
[3]   Self-activation of cellulose: A new preparation methodology for activated carbon electrodes in electrochemical capacitors [J].
Bommier, Clement ;
Xu, Rui ;
Wang, Wei ;
Wang, Xingfeng ;
Wen, David ;
Lu, Jun ;
Ji, Xiulei .
NANO ENERGY, 2015, 13 :709-717
[4]   Predicting capacity of hard carbon anodes in sodium-ion batteries using porosity measurements [J].
Bommier, Clement ;
Luo, Wei ;
Gao, Wen-Yang ;
Greaney, Alex ;
Ma, Shengqian ;
Ji, Xiulei .
CARBON, 2014, 76 :165-174
[5]   Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications [J].
Cao, Yuliang ;
Xiao, Lifen ;
Sushko, Maria L. ;
Wang, Wei ;
Schwenzer, Birgit ;
Xiao, Jie ;
Nie, Zimin ;
Saraf, Laxmikant V. ;
Yang, Zhengguo ;
Liu, Jun .
NANO LETTERS, 2012, 12 (07) :3783-3787
[6]   Fast synthesis of carbon microspheres via a microwave-assisted reaction for sodium ion batteries [J].
Chen, Taiqiang ;
Pan, Likun ;
Lu, Ting ;
Fu, Conglong ;
Chua, Daniel H. C. ;
Sun, Zhuo .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (05) :1263-1267
[7]   Sodium ion storage properties of WS2-decorated three-dimensional reduced graphene oxide microspheres [J].
Choi, Seung Ho ;
Kang, Yun Chan .
NANOSCALE, 2015, 7 (09) :3965-3970
[8]   Double-shelled hollow microspheres of LiMn2O4 for high-performance lithium ion batteries [J].
Ding, Yuan-Li ;
Zhao, Xin-Bing ;
Xie, Jian ;
Cao, Gao-Shao ;
Zhu, Tie-Jun ;
Yu, Hong-Ming ;
Sun, Cheng-Yue .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (26) :9475-9479
[9]   Nitrogen doped porous carbon fibres as anode materials for sodium ion batteries with excellent rate performance [J].
Fu, Lijun ;
Tang, Kun ;
Song, Kepeng ;
van Aken, Peter A. ;
Yu, Yan ;
Maier, Joachim .
NANOSCALE, 2014, 6 (03) :1384-1389
[10]   Nanostructured Mo-based electrode materials for electrochemical energy storage [J].
Hu, Xianluo ;
Zhang, Wei ;
Liu, Xiaoxiao ;
Mei, Yueni ;
Huang, Yunhui .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (08) :2376-2404