Palladium-catalyzed novel addition-elimination reaction of alkenyltin reagents to norbornene

被引：5
作者：
Fugami, K
Hirunuma, Y
Nishikata, T
Koyama, D
Kameyama, M
Kosugi, M
机构：
[1] Gunma Univ, Dept Chem, Kiryu, Gumma 3768515, Japan
[2] Oyama Natl Coll Technol, Oyama, Tochigi 3230806, Japan
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 687卷 / 02期
关键词：
palladium-catalyst; addition-elimination; Heck reaction; organotin reagent; halide;
D O I：
10.1016/j.jorganchem.2003.09.029
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Palladium-catalyzed reaction between 1-alkenyltin trichlorides and norbornene resulted in stereoselective formation of 3-alkylidenepentacyclo[9.2.1.(5.8)1.(1.11)0.(2.10)0(4.9)]pentadecane instead of an expected simple alkenylstannylation product. Generation of trichlorostannane and its decomposition product, tin(H) chloride, was confirmed by trapping it with methyl propiolate and norbornene and analysis of the reaction by Sn-119 NMR, respectively. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：567 / 569
页数：3
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