Fe-MIL-101 modified by isatin-Schiff-base-Co: a heterogeneous catalyst for C-C, C-O, C-N, and C-P cross coupling reactions

被引：13
|
作者：
Rouzifar, Majid [1 ]
Sobhani, Sara [1 ]
Farrokhi, Alireza [1 ]
Miguel Sansano, Jose [2 ,3 ]
机构：
[1] Univ Birjand, Coll Sci, Dept Chem, Birjand, Iran
[2] Univ Alicante, Fac Ciencias, Ctr Innovac Quim Avanzada ORFEO CINQA, Dept Quim Organ, Apdo 99, Alicante 03080, Spain
[3] Univ Alicante, Inst Sintesis Organ ISO, Apdo 99, Alicante 03080, Spain
来源：
NEW JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 42期
关键词：
METAL-ORGANIC FRAMEWORKS; POST-SYNTHETIC MODIFICATION; FLUORIDE-FREE HIYAMA; MIZOROKI-HECK; DIARYL ETHERS; ARYL HALIDES; RECYCLABLE CATALYST; EFFICIENT CATALYSTS; COBALT CATALYST; BOND FORMATION;
D O I：
10.1039/d1nj03468e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A metal-organic framework functionalized with a cobalt-complex is prepared via post-synthetic modification of Fe-MIL-101-NH2. Initially, Fe-MIL-101-NH2 reacted with isatin to produce Fe-MIL-101-isatin-Schiff-base, which can anchor the cobalt by the addition of cobalt acetate. The resulting MOF-Co catalyst is characterized by employing multiple techniques. This new modified MOF acts as a heterogeneous and recyclable catalyst for efficient Ullmann, Buchwald-Hartwig, Hirao, Hiyama and Mizoroki-Heck cross-coupling reactions of several aryl halides/phenylboronic acid/phenyltosylate with phenols, anilines/heterocyclic amines, triethyl phosphite, triethoxyphenylsilane and alkenes and generates the expected coupling products in good to high yields.
引用
收藏
页码：19963 / 19976
页数：14
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