The chemistry of the azanonaborane cluster RNH2-B8H11NHR

被引：5

作者：

Gabel, D ^{[1
]}

Bauer, C ^{[1
]}

El-Zaria, ME ^{[1
]}

Genady, AR ^{[1
]}

Dörfler, U ^{[1
]}

机构：

[1] Univ Bremen, Dept Chem, D-28334 Bremen, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 680卷 / 1-2期

关键词：

azanonaborane; boron neutron capture therapy; cluster rearrangement;

D O I：

10.1016/S0022-328X(03)00218-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and properties of the (RRNH)-R-1-N-2-B8H11NHR cluster are described. The cluster is stable to aqueous solutions and can be made water-soluble by the introduction of a few hydrophilic groups. This makes the cluster a good candidate as the boron moiety in compounds for boron neutron capture therapy. The chemistry of the cluster preparation, the stability of the cluster, and conditions for reactions of the organic moieties are reviewed. Pyridine derivatives of the cluster show electronic interaction between the cluster and the pyridine. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：23 / 26

页数：4

共 16 条

[1] A new class of carborane compounds for second-order nonlinear optics:: Ab initio molecular orbital study of hyperpolarizabilities for 1-(1′,X′-dicarba-closo-dodecaborane-1′-yl)-closo-dodecaborate dianion (X = 2,7,12) [J].