Growth and characterization of diaquatetrakis (thiocyanato) cobalt(II) mercury(II) N-methyl-2-pyrolidone (CMTWMP) single crystals

被引：13
作者：
Potheher, I. Vetha [1 ]
Madhavana, J. [1 ]
Rajarajan, K. [3 ]
Nagaraja, K. S. [2 ]
Sagayaraj, P. [1 ]
机构：
[1] Loyola Coll, Dept Phys, Madras 600034, Tamil Nadu, India
[2] Loyola Coll, Dept Chem, Madras 600034, Tamil Nadu, India
[3] RV Govt Arts Coll, Dept Phys, Chengalpattu 603001, India
来源：
JOURNAL OF CRYSTAL GROWTH | 2008年 / 310卷 / 01期
关键词：
organometallic; nonlinear optics; optical properties; blue-violet light;
D O I：
10.1016/j.jcrysgro.2007.10.022
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Single crystals of diaquatetrakis (thiocyanato) cobalt (II) mercury (II) N-methyl-2-pyrolidone, (CoHg(SCN)(4)center dot(H2O)(2)center dot 2(C3H6CONCH3) (abbreviated as CMTWMP) were grown using slow solvent evaporation technique. The structure of the grown crystals was confirmed by single-crystal X-ray diffraction (XRD) technique. The optical properties of the crystals were investigated by Fourier transform infrared (FTIR) and UV-Vis-NIR transmission spectra. The grown crystals of CMTWMP were also subjected to dielectric, photoconductivity, thermal and microhardness studies. The photoconductivity study of CMTWMP confirms the electrochromism behaviour in the sample. The SHG efficiency of the sample was measured by Kurtz and Perry powder technique and its value is almost comparable with KDP. (C) 2007 Elsevier B.V. All rights reserved.
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收藏
页码：124 / 130
页数：7
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