Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes

被引：46

作者：

Bidal, Yannick D. ^{[1
]}

Santoro, Orlando ^{[1
]}

Melaimi, Mohand ^{[2
]}

Cordes, David B. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Bertrand, Guy ^{[2
]}

Cazin, Catherine S. J. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Calif San Diego, Dept Chem & Biochem, UCSD CNRS Joint Res Lab UMI 3555, La Jolla, CA 92093 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 27期

基金：

英国工程与自然科学研究理事会;

关键词：

abnormal; CAAC; carbene transfer; copper; n-heterocyclic carbene; LIGANDS SYNTHESIS; COMPLEXES; PALLADIUM; CATALYSIS; CHEMISTRY; STABILIZATION; IMIDAZOLIUM; REACTIVITY; CHROMIUM; REMOTE;

D O I：

10.1002/chem.201601254

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbene transition-metal complexes have become a prevalent family of catalysts enabling numerous organic transformations. Their facile synthetic access is a matter of great importance. To this end, the Cu-I-NHC transfer methodology has emerged as a powerful alternative presenting attractive advantages over other methods. Herein, we report the remarkable ability of copper to transfer not only NHCs but also other types of carbenes such as abnormal NHCs (aNHCs), cyclic (alkyl)(amino)carbenes (CAACs), and mesoionic carbenes (MICs) to various transition metal precursors.

引用

页码：9404 / 9409

页数：6

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