Magnetically recyclable C@(Au@Fe) supported Pd nanoparticles for the Heck cross-coupling reactions

被引：11

作者：

Shen, Bin ^{[1
]}

Wang, Yongan ^{[1
]}

Wang, Zhifei ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China

来源：

REACTION KINETICS MECHANISMS AND CATALYSIS | 2010年 / 101卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Superparamagnet; Heck reaction; Pd nanoparticle; Carbon; CATALYST; SUZUKI; PALLADIUM;

D O I：

10.1007/s11144-010-0225-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Carbon encapsulated Au@Fe nanoparticles (NPs) were synthesized by the hydrothermal method, and the palladium NPs (12 nm) were immobilized on this hydroxyl-terminated support. The morphology, composition, content and magnetism of the samples were characterized. Compared with the commercial carbon-supported Pd catalyst, high catalytic activity, recyclability and selectivity were evaluated by the catalyst Pd/(C@(Au@Fe)) in the Heck reaction. Especially, in the Heck cross-coupling reactions of iodobenzene and methyl acrylate, the catalyst was reused 10 times without significant loss of activity. In addition, the catalyst was simply recycled by a magnetic field.

引用

页码：387 / 396

页数：10

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