Oxidative degradation of 2,4,6-trichlorophenol in the presence of air ions

被引:0
|
作者
Ma, HM
Wohlers, J
Meierhenrich, U
Bernecker, A
Suling, V
Thiemann, W
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Univ Bremen, Dept Chem, D-28334 Bremen, Germany
关键词
2,4,6-trichlorophenol; air ions; electric discharge; oxidative degradation; pollutant treatment;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2,4,6-trichlorophenol (TCP) was firstly treated with air ions generated by electric discharge, and high dechlorination (53%) was observed after 60 min treatment, indicating that air ions are an efficient dechlorination means and might have a future in the oxidative removal of chlorinated phenols. In addition, a stepwise degradation of TCP, beginning with the formation of a major product 2,6-dichloro-1,4-benzenediol via substitution, is proposed through a detailed analysis of gas chromatography/mass spectrometry.
引用
收藏
页码:211 / 214
页数:4
相关论文
共 16 条
  • [1] Oxidative Degradation of 2,4,6-Trichlorophenolin the Presence of Air Ions
    Hui Min MA1*
    Chinese Chemical Letters, 2001, (03) : 211 - 214
  • [2] Mechanism of catalytic degradation of 2,4,6-trichlorophenol by a Fe-porphyrin catalyst
    Christoforidis, Konstantinos C.
    Serestatidou, Eleni
    Louloudi, Maria
    Konstantinou, Ioannis K.
    Milaeva, Elena R.
    Deligiannakis, Yiannis
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 101 (3-4) : 417 - 424
  • [3] Degradation of 2,4,6-trichlorophenol with peroxymonosulfate catalyzed by soluble and supported iron porphyrins
    Gunay, Tugce
    Cimen, Yasemin
    ENVIRONMENTAL POLLUTION, 2017, 231 : 1013 - 1020
  • [4] Decomposition of 2-chlorophenol, 4-chlorophenol and 2,4,6-trichlorophenol by catalytic oxidation over cobalt and nickel impregnated SBA-15
    Mayani, Suranjana V.
    Mayani, Vishal J.
    Kim, Sang Wook
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2013, 91 (07) : 1270 - 1280
  • [5] Oxidative degradation of acid doped polybenzimidazole membranes and fuel cell durability in the presence of ferrous ions
    Liao, Jianhui
    Yang, Jingshuai
    Li, Qingfeng
    Cleemann, Lars N.
    Jensen, Jens Oluf
    Bjerrum, Niels J.
    He, Ronghuan
    Xing, Wei
    JOURNAL OF POWER SOURCES, 2013, 238 : 516 - 522
  • [6] NMR Study on the Oxidative Degradation of MEA in Presence of Fe2+
    Ciftja, Arlinda F.
    Hartono, Ardi
    Grimstvedt, Andreas
    Svendsen, Hallvard F.
    6TH TRONDHEIM CONFERENCE ON CO2 CAPTURE, TRANSPORT AND STORAGE, 2012, 23 : 111 - 118
  • [7] Mechanisms of MoS2 formation by MoDTC in presence of ZnDTP:: effect of oxidative degradation
    Bouchet, MID
    Martin, JM
    Le Mogne, T
    Bilas, P
    Vacher, B
    Yamada, Y
    WEAR, 2005, 258 (11-12) : 1643 - 1650
  • [8] Oxidative degradation of norfloxacin by water soluble colloidal MnO2 in the presence of cationic surfactant
    Singh, Ajaya Kumar
    Sen, Neelam
    Chatterjee, Som Kumar
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2016, 55 (09): : 1059 - 1067
  • [9] The mechanism of 2-chlorobiphenyl oxidative degradation by nanoscale zero-valent iron in the presence of dissolved oxygen
    Yu Wang
    Linhao Liu
    Guodong Fang
    Lei Wang
    Fredrick Orori Kengara
    Changyin Zhu
    Environmental Science and Pollution Research, 2018, 25 : 2265 - 2272
  • [10] The mechanism of 2-chlorobiphenyl oxidative degradation by nanoscale zero-valent iron in the presence of dissolved oxygen
    Wang, Yu
    Liu, Linhao
    Fang, Guodong
    Wang, Lei
    Kengara, Fredrick Orori
    Zhu, Changyin
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2018, 25 (03) : 2265 - 2272