On the growth mechanism of a-Si:H

被引:77
作者
Kessels, WMM
Smets, AHM
Marra, DC
Aydil, ES
Schram, DC
van de Sanden, MCM
机构
[1] Eindhoven Univ Technol, Dept Appl Phys, NL-5600 MB Eindhoven, Netherlands
[2] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA
关键词
a-Si : H; growth model; SiH3; radicals; surface reactions; H elimination;
D O I
10.1016/S0040-6090(00)01594-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The kinetic growth model for hydrogenated amorphous silicon (a-Si:H) from SiH4 radicals in SiH4 plasmas is reviewed on the basis of recently obtained experimental and computational data. New surface reactions are considered and their implications for the a-Si:H film growth mechanism are discussed. Furthermore, from the experimentally observed substrate temperature-dependence of the bulk hydrogen content and the composition of the a-Si:H surface hydrides, it is concluded that surface processes play an important role in hydrogen elimination from the him during growth. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:154 / 160
页数:7
相关论文
共 37 条
[1]   Kinetics of D abstraction with H atoms from the monodeuteride phase on Si(100) surfaces [J].
Dinger, A ;
Lutterloh, C ;
Küppers, J .
CHEMICAL PHYSICS LETTERS, 1999, 311 (3-4) :202-208
[2]   Growth mechanism of hydrogenated amorphous silicon studied by in situ scanning tunneling microscopy [J].
Flewitt, AJ ;
Robertson, J ;
Milne, WI .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (12) :8032-8039
[3]  
GALLAGHER A, 1986, MATER RES SOC S P, V70, P3
[4]   DEFECT FORMATION DURING GROWTH OF HYDROGENATED AMORPHOUS-SILICON [J].
GANGULY, G ;
MATSUDA, A .
PHYSICAL REVIEW B, 1993, 47 (07) :3661-3670
[5]   SURFACE-REACTIONS DURING THE A-SI-H GROWTH IN THE DIODE AND TRIODE GLOW-DISCHARGE REACTORS [J].
GUIZOT, JL ;
NOMOTO, K ;
MATSUDA, A .
SURFACE SCIENCE, 1991, 244 (1-2) :22-38
[6]   LIFETIME OF AN ADSORBATE-SUBSTRATE VIBRATION - H ON SI(111) [J].
GUYOTSIONNEST, P ;
DUMAS, P ;
CHABAL, YJ ;
HIGASHI, GS .
PHYSICAL REVIEW LETTERS, 1990, 64 (18) :2156-2159
[7]   HYDROGEN ELIMINATION DURING THE GLOW-DISCHARGE DEPOSITION OF A-SI-H ALLOYS [J].
KAMPAS, FJ ;
GRIFFITH, RW .
APPLIED PHYSICS LETTERS, 1981, 39 (05) :407-409
[8]   Temperature and growth-rate effects on the hydrogen incorporation in a-Si:H [J].
Kessels, WMM ;
Severens, RJ ;
van de Sanden, MCV ;
Schram, DC .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 227 :133-137
[9]  
KESSELS WMM, 2000, MAT RES SOC S P, V609
[10]   Morphological study of kinetic roughening on amorphous and microcrystalline silicon surface [J].
Kondo, M ;
Ohe, T ;
Saito, K ;
Nishimiya, T ;
Matsuda, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 227 :890-895