Effect of Ag/rGO on the Optical Properties of Plasmon-Modified SnO2 Composite and Its Application in Self-Powered UV Photodetector

被引:14
作者
Abdalla, James Taban [1 ,2 ]
Wang, Jinzhong [1 ]
Wang, Dongbo [1 ]
机构
[1] Harbin Inst Technol, Dept Optoelect Informat Sci, Sch Mat Sci & Engn, Harbin 150001, Peoples R China
[2] Univ Juba, Sch Appl & Ind Sci, POB 80 Buluk, Juba City, South Sudan
基金
中国国家自然科学基金; 黑龙江省自然科学基金;
关键词
UV photodetector; surface plasmon; Ag; rGO; SnO2; nanorod; plasmon-modified-SnO2; composite; SIZE-CONTROLLED SYNTHESIS; REDUCED GRAPHENE OXIDE; SENSITIZED SOLAR-CELLS; HIGH-PERFORMANCE; SURFACE; TIO2; NANOPARTICLES; DYE; ZNO; PHOTOCATALYST;
D O I
10.3390/cryst9120648
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A facile hydrothermal method was employed to synthesize silver-reduced graphene oxide (Ag/rGO) plasmon-modified SnO2 composite, by incorporating Ag-reduced graphene oxide (Ag/rGO) into SnO2 nanorods as a photoanode for assembling a self-powered ultraviolet photodetector (UVPD). The as-synthesized samples were investigated in detail by X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, and UV visible spectrophotometer. The as-prepared Ag/rGO films show enhanced light absorption attributed to the localized surface plasmon resonance (LSPR). The optimized 1.0 wt.% Ag/rGO incorporated into SnO2-based UVPD exhibits a significant photocurrent response due to the enhanced absorption light and effective suppression of charge recombination. This UVPD demonstrates a high performance, with photocurrent density reaching 0.29 mAcm(-2) compared to the SnO2-based device with 0.16 mAcm(-2). This device also exhibits a high on:off ratio of 195 and fast response time, which are superior to that of the free-modified one. In addition, the UVPD based on plasmon-modified SnO2 photoanode treated with TiCl4-aqueous solution has attained a higher photocurrent with a maximum value reaching 5.4 mAcm(-2), making this device favorable in ultraviolet detection.
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页数:14
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