The reaction of MoCl4 with TeCl4: Synthesis and crystal structure of tris(trichlorotelluronium) hexachloromolybdate(IV) chloride, ([TeCl3](+))(3)[MoCl6](2-)[Cl-]

被引：5

作者：

Beck, J

机构：

[1] Inst. F. Anorganische Analyt. Chem., Justus-Liebig-Universität, D - 35392 Gießen

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 08期

关键词：

trichlorotelluronium; hexachloromolybdate(IV); synthesis; crystal Structure;

D O I：

10.1515/znb-1996-0811

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Red crystals of (TeCl3)(3) MoCl6(Cl) are obtained by reacting MoCl4 with TeCl4 in a 1:3 molar ratio in a sealed evacuated ampoule at 170 degrees. The crystal structure determination (orthorhombic, space group Cmc2(1), a = 1541.6(2), b = 1268.1(1), c = 1180.6(1) pm) shows the presence of trigonal-pyramidal [TeCl3](+) ions, octahedral [MoCl6](2-) ions, and isolated Cl- ions. The ions are linked by long Te-Cl bridges resulting in distorted TeCl6 octahedra. The octahedra are connected by joint edges and corners to zig-zag chains running along the polar c axis.

引用

页码：1127 / 1131

页数：5

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