Crystal polymorphism in 1-butyl-3-methylimidazolium halides: supporting ionic liquid formation by inhibition of crystallization

被引：369
作者：
Holbrey, JD [1 ]
Reichert, WM
Nieuwenhuyzen, M
Johnston, S
Seddon, KR
Rogers, RD
机构：
[1] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA
[2] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
[3] Queens Univ Belfast, Dept Chem, Belfast BT9 5AG, Antrim, North Ireland
[4] Queens Univ Belfast, QUILL, Belfast BT9 5AG, Antrim, North Ireland
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 14期
关键词：
D O I：
10.1039/b304543a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Crystallization of 1-butyl-3-methylimidazolium chloride from mixed ionic liquid or ionic liquid-aromatic solution, and from the melt yields different crystalline polymorphs, the first direct evidence for inhibition of crystallization in ionic liquids by polymorphism.
引用
收藏
页码：1636 / 1637
页数：2
相关论文
共 22 条
  • [11] FUSED ORGANIC SALTS .8. PROPERTIES OF MOLTEN STRAIGHT-CHAIN ISOMERS OF TETRA-NORMAL-PENTYLAMMONIUM SALTS
    GORDON, JE
    SUBBARAO, GN
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (24) : 7445 - 7454
  • [12] Structure of molten 1,3-dimethylimidazolium chloride using neutron diffraction
    Hardacre, C
    Holbrey, JD
    McMath, SEJ
    Bowron, DT
    Soper, AK
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2003, 118 (01) : 273 - 278
  • [13] Gold compounds as ionic liquids.: Synthesis, structures, and thermal properties of N,N′-dialkylimidazolium tetrachloroaurate salts
    Hasan, M
    Kozhevnikov, IV
    Siddiqui, MRH
    Steiner, A
    Winterton, N
    [J]. INORGANIC CHEMISTRY, 1999, 38 (25) : 5637 - 5641
  • [14] Raman spectra, crystal polymorphism, and structure of a prototype ionic-liquid [bmim]Cl
    Hayashi, S
    Ozawa, R
    Hamaguchi, H
    [J]. CHEMISTRY LETTERS, 2003, 32 (06) : 498 - 499
  • [15] Efficient, halide free synthesis of new, low cost ionic liquids: 1,3-dialkylimidazolium salts containing methyl- and ethyl-sulfate anions
    Holbrey, JD
    Reichert, WM
    Swatloski, RP
    Broker, GA
    Pitner, WR
    Seddon, KR
    Rogers, RD
    [J]. GREEN CHEMISTRY, 2002, 4 (05) : 407 - 413
  • [16] Liquid clathrate formation in ionic liquid-aromatic mixtures
    Holbrey, JD
    Reichert, WM
    Nieuwenhuyzen, M
    Sheppard, O
    Hardacre, C
    Rogers, RD
    [J]. CHEMICAL COMMUNICATIONS, 2003, (04) : 476 - 477
  • [17] The phase behaviour of 1-alkyl-3-methylimidazolium tetrafluoroborates; ionic liquids and ionic liquid crystals
    Holbrey, JD
    Seddon, KR
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (13): : 2133 - 2139
  • [18] Ionic liquids: perspectives for organic and catalytic reactions
    Olivier-Bourbigou, H
    Magna, L
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 182 (01) : 419 - 437
  • [19] Rogers R. D., 2002, ACS S SERIES, V818
  • [20] SAHA S, 2003, CHEM LETT, V32
123