Excited state absorption: a key phenomenon for the improvement of biphotonic based optical limiting at telecommunication wavelengths

被引：85

作者：

Bellier, Quentin ^{[1
]}

Makarov, Nikolay S. ^{[2
]}

Bouit, Pierre-Antoine ^{[1
]}

Rigaut, Stephane ^{[3
]}

Kamada, Kenji ^{[4
]}

Feneyrou, Patrick ^{[5
]}

Berginc, Gerard ^{[5
]}

Maury, Olivier ^{[1
]}

Perry, Joseph W. ^{[2
]}

Andraud, Chantal ^{[1
]}

机构：

[1] Univ Lyon 1, Ecole Normale Super Lyon, CNRS, UMR 5182, F-69364 Lyon 07, France

[2] Georgia Inst Technol, Sch Chem & Biochem, Ctr Organ Photon & Elect, Atlanta, GA 30332 USA

[3] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France

[4] Natl Inst Adv Ind Sci & Technol, AIST Kansai Ctr, Res Inst Ubiquitous Energy Devices, Ikeda, Osaka 5638577, Japan

[5] Thales Res & Technol France, F-91767 Palaiseau, France

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2012年 / 14卷 / 44期

关键词：

2-PHOTON ABSORPTION; NONLINEAR ABSORPTION; SYMMETRY-BREAKING; PORPHYRIN ARRAYS; POLYMETHINE DYES; RANGE; FLUORESCENCE; CHROMOPHORES; ENHANCEMENT; SQUARAINE;

D O I：

10.1039/c2cp40779e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Spectroscopic properties, two-photon absorption (TPA) and excited state absorption (ESA), of two organic cyanine dyes and of a ruthenium based organometallic cyanine are compared in order to rationalize their similar ns-optical power limiting (OPL) efficiency in the telecommunication wavelength range. The TPA contribution to the ns-OPL behavior is higher for both organic cyanines, while the main process is a TPA-induced ESA in the case of the organometallic system, in which the ruthenium induces a broadening of the NIR-ESA band and resulting in a strong spectral overlap between TPA and ESA spectra.

引用

页码：15299 / 15307

页数：9

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