N,N-Dimethylformamide: A Multipurpose Building Block

被引：396
作者：
Ding, Shengtao [1 ]
Jiao, Ning [1 ,2 ]
机构：
[1] Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
[2] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 37期
关键词：
amines; cyanides; heterocycles; nitrogen; synthetic methods; PALLADIUM-CATALYZED CYANATION; MONOXIDE-FREE AMINOCARBONYLATION; ONE-POT CONVERSION; C-H ACTIVATION; ARYL HALIDES; AROMATIC NITRILES; ORGANIC-SYNTHESIS; CYANIDE SOURCE; HETEROGENEOUS CATALYST; DIRECT TRANSFORMATION;
D O I：
10.1002/anie.201200859
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Often used as a common solvent for chemical reations and utilized widely in industry as a reagent, N,N-dimethylformamide (DMF) has played an important role in organic synthesis for a long time. Numerous highly useful articles and reviews discussing its utilizations have been published. With a focus on the performance of DMF as a multipurpose precursor for various units in numerous reactions, this Minireview summarizes recent developments in the employment of DMF in the fields of formylation, aminocarbonylation, amination, amidation, and cyanation, as well as its reaction with arynes.
引用
收藏
页码：9226 / 9237
页数：12
相关论文
共 133 条
[1]   Convenient dimethylamino amination in heterocycles and aromatics with dimethylformamide [J].
Agarwal, A ;
Chauhan, PMS .
SYNTHETIC COMMUNICATIONS, 2004, 34 (16) :2925-2930
[2]   Associative transmetalation in the stille cross-coupling reaction to form dienes:: Theoretical insights into the open pathway [J].
Alvarez, Rosana ;
Perez, Martin ;
Faza, Olalla Nieto ;
de Lera, Angel R. .
ORGANOMETALLICS, 2008, 27 (14) :3378-3389
[3]  
[Anonymous], 2008, ANGEW CHEM
[4]  
[Anonymous], 2010, ANGEW CHEM
[5]  
Arai S., 2009, ANGEW CHEM, V121, P4598
[6]   Catalytic Dicyanative 5-exo- and 6-endo-Cyclization Triggered by Cyanopalladation of Alkynes [J].
Arai, Shigeru ;
Koike, Yuka ;
Nishida, Atsushi .
ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (05) :893-900
[7]   Catalytic 1,2-Dicyanation of Alkynes by Palladium(II) under Aerobic Conditions [J].
Arai, Shigeru ;
Sato, Takashi ;
Nishida, Atsushi .
ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (11-12) :1897-1904
[8]   Palladium-Catalyzed Cyanation of Carbon-Carbon Triple Bonds Under Aerobic Conditions [J].
Arai, Shigeru ;
Sato, Takashi ;
Koike, Yuka ;
Hayashi, Michino ;
Nishida, Atsushi .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (25) :4528-4531
[9]   Unprecedented heptacopper(II) cluster with body-centred anti-prismatic topology. Structure, magnetism and density functional study [J].
Arora, Himanshu ;
Cano, Joan ;
Lloret, Francesc ;
Mukherjee, Rabindranath .
DALTON TRANSACTIONS, 2011, 40 (39) :10055-10062
[10]   Facile synthesis of pegylated zinc(II) phthalocyanines via transesterification and their in vitro photodynamic activities [J].
Bai, Ming ;
Lo, Pui-Chi ;
Ye, Jing ;
Wu, Chi ;
Fong, Wing-Ping ;
Ng, Dennis K. P. .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2011, 9 (20) :7028-7032
12345678910