N,N-Dimethylformamide: A Multipurpose Building Block

被引：383
|
作者：
Ding, Shengtao [1 ]
Jiao, Ning [1 ,2 ]
机构：
[1] Peking Univ, State Key Lab Nat & Biomimet Drugs, Sch Pharmaceut Sci, Beijing 100191, Peoples R China
[2] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 37期
关键词：
amines; cyanides; heterocycles; nitrogen; synthetic methods; PALLADIUM-CATALYZED CYANATION; MONOXIDE-FREE AMINOCARBONYLATION; ONE-POT CONVERSION; C-H ACTIVATION; ARYL HALIDES; AROMATIC NITRILES; ORGANIC-SYNTHESIS; CYANIDE SOURCE; HETEROGENEOUS CATALYST; DIRECT TRANSFORMATION;
D O I：
10.1002/anie.201200859
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Often used as a common solvent for chemical reations and utilized widely in industry as a reagent, N,N-dimethylformamide (DMF) has played an important role in organic synthesis for a long time. Numerous highly useful articles and reviews discussing its utilizations have been published. With a focus on the performance of DMF as a multipurpose precursor for various units in numerous reactions, this Minireview summarizes recent developments in the employment of DMF in the fields of formylation, aminocarbonylation, amination, amidation, and cyanation, as well as its reaction with arynes.
引用
收藏
页码：9226 / 9237
页数：12
相关论文
共 50 条
  • [1] N,N-DIMETHYLFORMAMIDE (DMF)
    DOI, S
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1982, 40 (05) : 446 - 446
  • [2] CROSS ENTHALPIC PAIR INTERACTION COEFFICIENTS WITH WATER IN N,N-DIMETHYLFORMAMIDE AND WITH N,N-DIMETHYLFORMAMIDE IN WATER
    BLOEMENDAL, M
    ROUW, AC
    SOMSEN, G
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 : 53 - 60
  • [3] ELECTROCHEMILUMINESCENCE OF AROMATICS IN N,N-DIMETHYLFORMAMIDE
    MORI, K
    YAMAMOTO, N
    TSUBOMUR.H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1971, 44 (10) : 2661 - +
  • [4] SOLUBILITY OF NITROBENZANILIDES IN N,N-DIMETHYLFORMAMIDE
    MYASNIKO.LF
    BUSHINSK.VI
    FROLOVA, TI
    VAISMAN, IL
    NOVOKHAT.DA
    FREIDLIN, GN
    ZHURNAL PRIKLADNOI KHIMII, 1973, 46 (03) : 691 - 693
  • [5] NUCLEOPHILIC ACTIVITY OF N,N-DIMETHYLFORMAMIDE
    KUZNETSOV, VA
    GARABADZHIU, AV
    GINZBURG, OF
    ZHURNAL ORGANICHESKOI KHIMII, 1986, 22 (02): : 455 - 456
  • [6] POLYMERIZATION OF STYRENE IN N,N-DIMETHYLFORMAMIDE
    GEORGE, MH
    WARD, JR
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1973, 11 (02) : 377 - 387
  • [7] Reaction of chloropyridazines with N,N-dimethylformamide
    Lee, WS
    Yoon, YJ
    Kim, SK
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2000, 37 (06) : 1591 - 1595
  • [8] CATHODE BEHAVIOR OF N,N-DIMETHYLFORMAMIDE
    BUKHTIAROV, AV
    LEBEDEV, AV
    KUDRYAVTSEV, YG
    GOLYSHIN, VN
    SHESTAKOVA, TA
    MIKHEEV, VV
    ZHURNAL OBSHCHEI KHIMII, 1991, 61 (04): : 965 - 969
  • [9] Hydrochlorothiazide N,N-dimethylformamide solvate
    Johnston, A
    Florence, AJ
    Kennedy, AR
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O1730 - O1732
  • [10] PERIODATE OXIDATION IN N,N-DIMETHYLFORMAMIDE
    GUTHRIE, RD
    CHEMISTRY & INDUSTRY, 1960, (24) : 691 - 691
12345