Pd-Catalyzed Borylsilylative Cyclization of 1,6-Allenynes

被引:3
|
作者
Zhang, Yinchao [1 ]
Xu, Wenxiu [2 ]
Gao, Tongtong [2 ]
Guo, Mengjuan [2 ]
Yang, Chun-Hua [2 ]
Xie, Hua [3 ]
Kong, Xiangtao [2 ]
Yang, Zhantao [2 ]
Chang, Junbiao [1 ]
机构
[1] Henan Normal Univ, Sch Chem & Chem Engn, NMPA Key Lab Res & Evaluat Innovat Drug, Henan Key Lab Organ Funct Mol & Drug Innovat, Xinxiang 453007, Henan, Peoples R China
[2] Anyang Normal Univ, Coll Chem & Chem Engn, Henan Key Lab New Optoelect Funct Mat, Anyang 455000, Peoples R China
[3] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
SILABORATIVE CARBOCYCLIZATIONS; CYCLOISOMERIZATIONS; CHIRALITY; ACTIVATION; MECHANISM; ADDITIONS; ALKYNES; LIGAND; ENYNES; BONDS;
D O I
10.1021/acs.orglett.2c02878
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A Pd-catalyzed borylsilylative cyclization of 1,6-allenynes with PhMe2SiBpin was developed. This method provides a practical and general method to afford the carbocycles and heterocycles bearing silyl and boryl groups with excellent regioselectivities and stereoselectivities in high to excellent yields.
引用
收藏
页码:7021 / 7025
页数:5
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