Nanosheet-Constructed Porous TiO2-B for Advanced Lithium Ion Batteries

被引：345

作者：

Liu, Shaohua ^{[1
]}

Jia, Haiping ^{[1
]}

Han, Lu ^{[1
]}

Wang, Jiulin ^{[1
]}

Gao, Pengfei ^{[1
]}

Xu, Dongdong ^{[1
]}

Yang, Jun ^{[1
]}

Che, Shunai ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Compos, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

来源：

ADVANCED MATERIALS | 2012年 / 24卷 / 24期

基金：

中国国家自然科学基金;

关键词：

TiO2-B; nanosheets; porous structures; lithium ion batteries; anode materials; TITANATE NANOSHEETS; SANDWICH-LIKE; TIO2(B); ANATASE; NANOTUBES; INTERCALATION; MICROSPHERES; ELECTRODES; CAPACITY; ANODE;

D O I：

10.1002/adma.201201036

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hierarchical porous TiO2-B with thin nanosheets is successfully synthesized. TiO2-B polymorph ensures fast insertion of Li-ion due to its pseudocapacitive mechanism. The thin nanosheet walls with porous structure allow exposure to electrolytes for facile ionic transport and interfacial reaction. The joint advantages endow this material with high reversible capacity, excellent cycling performance, and superior rate capability.

引用

页码：3201 / 3204

页数：4

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