Anion directed assembly of a dinuclear double helicate

被引:97
|
作者
Keegan, J
Kruger, PE [1 ]
Nieuwenhuyzen, M
O'Brien, J
Martin, N
机构
[1] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland
[2] Royal Coll Surgeons Ireland, Dept Chem, Dublin 2, Ireland
[3] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland
关键词
D O I
10.1039/b106981k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and structural characterisation of the diamino-bis-pyridine ligand L-2 and its diammonium-bis-pyridinium salt [((H4LCl)-Cl-2)(2)]. 6Cl .H2O 1, are reported; X-ray diffraction studies reveal that chloride coordination causes the latter to adopt a double-helicate structure in the solid-state.
引用
收藏
页码:2192 / 2193
页数:2
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