Unusual cadmium(II)-adenine paddle-wheel units for the construction of a metal-organic framework with mog topology

被引：20
|
作者：
Wang, Fei [1 ]
Kang, Yao [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 20卷
关键词：
Metal-organic framework; Topology; SBUs; Paddle wheel; MICROPOROUS FRAMEWORK; ACHIRAL PRECURSORS; NUCLEOBASE; ADENINE; CRYSTALLIZATION; COORDINATION; CATALYSIS; DESIGN; NETS;
D O I：
10.1016/j.inoche.2012.03.023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new three-dimensional (3D) metal-organic framework [Cd-2(Ad)(2)(IN)(2)(DMF) (H2O)]center dot DMF (1; Ad = Adenine: IN = isonicotinic acid) with unusual cadmium-adeninate "paddle-wheel" building block has been solvothermally synthesized and structurally characterized by single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermogravimetric analysis (TG) Elemental analysis (EA) and Infrared Spectroscopy (IR). Compound 1 exhibits 4-connected moganite (mog) topologic network. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：266 / 268
页数：3
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