Direct synthesis of amphiphilic alpha-, beta-, and gamma-cyclodextrins

被引：16

作者：

Chmurski, K

Coleman, AW

Jurczak, J

机构：

[1] POLISH ACAD SCI,INST ORGAN CHEM,PL-01224 WARSAW,POLAND

[2] UNIV WARSAW,DEPT CHEM,PL-02093 WARSAW,POLAND

[3] INST BIOL & CHIM PROT,CNRS UPR412,F-69367 LYON,FRANCE

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1996年 / 15卷 / 07期

关键词：

D O I：

10.1080/07328309608005692

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The clean one step synthesis of the amphiphilic alpha-, beta-, and gamma-cyclodextrins starting from per-(6-bromo-6-deoxy)-alpha-, -beta-, and -gamma-cyclodextrins is described. The role of the lipophilic tail is played by various aryl groups (phenyl, p-bromophenyl, p-O-butoxyphenyl, p-pentylphenyl, and o-, m-, and p-nitrophenyl) linked by a thioether bridge to the position C-6 of each glucopyranose unit. The yields of the S-alkylation reactions were very high (85-95%).

引用

页码：787 / 796

页数：10

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