Optical properties of cadmium sulfide colloidal dispersions prepared by interphase synthesis

被引:10
作者
Kudlash, Alexander N. [1 ]
Vorobyova, Svetlana A. [2 ]
Lesnikovich, Anatoly I. [2 ]
Kukhta, Alexander V. [3 ]
Kolesnik, Eduard E. [3 ]
机构
[1] Belarusian State Univ, Dept Chem, Minsk 220030, BELARUS
[2] Belarusian State Univ, Phys Chem Problems Res Inst, Minsk 220030, BELARUS
[3] Natl Acad Sci Belarus, Inst Atom & Mol Phys, Minsk 220072, BELARUS
关键词
CdS; nanoparticles; optical properties; luminescence; chemical synthesis; transmission electron microscopy;
D O I
10.1016/j.optmat.2007.06.011
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Cadmium sulfide stable colloidal dispersions in hexane, toluene and toluene solution of polystyrene or polyepoxypropylcarbazole have been obtained by the interphase interaction of cadmium oleate and sodium or hydrogen sulfide dissolved in organic solvent and water, respectively. The effect of the precipitant nature and starting molar ratio Cd2+/S2- on the properties of the dispersions have been investigated. CdS nanoparticles exhibited relatively uniform size distribution at about 3 nm and crystal cubic structure. The optical properties of the dispersions have been studied by absorption spectroscopy and photoluminescence. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1304 / 1309
页数:6
相关论文
共 21 条
[1]   Synthesis of size-tunable and stable CdS nanocrystals in DMF [J].
Babu, KS ;
Vijayan, C ;
Haridoss, P .
MATERIALS LETTERS, 2006, 60 (01) :124-128
[2]   SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].
BRUST, M ;
WALKER, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
WHYMAN, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802
[3]   NOVEL GOLD-DITHIOL NANO-NETWORKS WITH NONMETALLIC ELECTRONIC-PROPERTIES [J].
BRUST, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
KIELY, CJ .
ADVANCED MATERIALS, 1995, 7 (09) :795-&
[4]   Optical properties of US nanoparticles and the energy transfer from US nanoparticles to Rhodamine 6G [J].
Chowdhury, PS ;
Sen, P ;
Patra, A .
CHEMICAL PHYSICS LETTERS, 2005, 413 (4-6) :311-314
[5]   Preparation of cadmium sulfide nanoparticles in self-reproducing reversed micelles [J].
Dutta, P ;
Fendler, JH .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 247 (01) :47-53
[6]  
JIANXI Y, 2003, MICROELECTRON ENG, V66, P115, DOI DOI 10.1016/S0167-9317(03)00034-0
[7]   Comparative study of dodecanethiol-derivatized silver nanoparticles prepared in one-phase and two-phase systems [J].
Kang, SY ;
Kim, K .
LANGMUIR, 1998, 14 (01) :226-230
[8]   Stable light emission from cadmium sulphide quantum dots in N,N′,-dimethylformamide [J].
Khanna, PK ;
Gokhale, R ;
Subbarao, VVVS .
MATERIALS LETTERS, 2003, 57 (16-17) :2489-2493
[9]   Optical and electrophysical properties of Ag-PEPC nanocomposites [J].
Kukhta, A. V. ;
Kolesnik, E. E. ;
Lesnikovich, A. I. ;
Nichick, M. N. ;
Ritchik, D. V. ;
Vorobyova, S. A. .
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2006, 26 (5-7) :1012-1016
[10]   Synthesis and characterization of hydrophobic, organically-soluble gold nanocrystals functionalized with primary amines [J].
Leff, DV ;
Brandt, L ;
Heath, JR .
LANGMUIR, 1996, 12 (20) :4723-4730