Bicyclic sesquiterpenoids as maturity indicator in oils of Qingdong Sag, Bohai Bay Basin, China

被引:1
作者
Ge, Haixia [1 ]
Zhang, Zhihuan [2 ]
Min, Wei [3 ]
机构
[1] Shaanxi Yanchang Petr Grp Co LTD, Res Inst, Xian 710075, Shaanxi, Peoples R China
[2] China Univ Petr, State Key Lab Petr Resource & Prospecting, Beijing, Peoples R China
[3] Shengli Oilfield Co, SINOPEC, Petr Dev Inst, Dongying, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
bicyclic sesquiterpenoids; Immature oils; 4,4,8,9,9-pentamethyl decahydronaphthalene /8 beta(H)-homodrimane; maturity indicator; Qingdong sag; ORGANIC-MATTER;
D O I
10.1080/10916466.2017.1391842
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Immature oils were proved to be existed in Es-4(u) reservoirs based on GC-MS and carbon isotope analysis of oil sand and source rocks in Qingdong sag. By comprehensive discussion with compositional data from different sags in China, bicyclic sesquiterpenoids are related to thermal maturity and can be used in oil maturity identification. A new indicator, 4,4,8,9,9-pentamethyl decahydronaphthalene/ 8 beta(H)-homodrimane, is proposed for distinguishing immature and mature oils in the study area. It signifies mature when this ratio value is higher than 0.34, and immature when the value is lower than 0.34. The varying structures of the two compounds determines their stability.
引用
收藏
页码:2172 / 2178
页数:7
相关论文
共 17 条
[1]   THE EFFECTS OF THERMAL MATURITY ON DISTRIBUTIONS OF DIMETHYLNAPHTHALENES AND TRIMETHYLNAPHTHALENES IN SOME ANCIENT SEDIMENTS AND PETROLEUMS [J].
ALEXANDER, R ;
KAGI, RI ;
ROWLAND, SJ ;
SHEPPARD, PN ;
CHIRILA, TV .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1985, 49 (02) :385-395
[2]  
Alexander R., 1984, Organic Geochemistry, V6, P63, DOI [10.1016/0146-6380(84)90027-5, DOI 10.1016/0146-6380(84)90027-5]
[3]   CYCLOALKANE CONSTITUENTS OF BITUMEN FROM GREEN RIVER SHALE [J].
ANDERS, DE ;
ROBINSON, WE .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1971, 35 (07) :661-&
[4]  
[Anonymous], BIOMARKER GUIDE INTE
[5]   Distribution of alkylated dibenzothiophenes in petroleum as a tool for maturity assessments [J].
Chakhmakhchev, A ;
Suzuki, M ;
Takayama, K .
ORGANIC GEOCHEMISTRY, 1997, 26 (7-8) :483-489
[6]   MATURITY DETERMINATION OF ORGANIC-MATTER IN COALS USING THE METHYLPHENANTHRENE DISTRIBUTION [J].
KVALHEIM, OM ;
CHRISTY, AA ;
TELNAES, N ;
BJORSETH, A .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1987, 51 (07) :1883-1888
[7]  
Luo BJ, 1990, Sci China Ser B, V4, P419
[8]  
PHILP RP, 1981, GEOCHIM COSMOCHIM AC, V45, P1173
[9]   GEOCHEMICAL STUDY ON A WELL IN THE WESTERN CANADA BASIN - RELATION OF THE AROMATIC DISTRIBUTION PATTERN TO MATURITY OF ORGANIC-MATTER [J].
RADKE, M ;
WELTE, DH ;
WILLSCH, H .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1982, 46 (01) :1-10
[10]  
[时丕同 SHI Pi-tong], 2009, [西南石油大学学报.自然科学版, Journal of Southwest Petroleum University], V31, P43