Synthesis of Schiff's bases in aqueous medium: a green alternative approach with effective mass yield and high reaction rates

被引：63

作者：

Rao, V. Koteswara ^{[1
]}

Reddy, S. Subba ^{[1
]}

Krishna, B. Satheesh ^{[1
]}

Naidu, K. Reddi Mohan ^{[1
]}

Raju, C. Naga ^{[1
]}

Ghosh, S. K. ^{[2
]}

机构：

[1] Sri Venkateswara Univ, Dept Chem, Tirupati 517502, Andhra Pradesh, India

[2] Bhabha Atom Res Ctr, Div Bioorgan, Bombay 400085, Maharashtra, India

来源：

GREEN CHEMISTRY LETTERS AND REVIEWS | 2010年 / 3卷 / 03期

关键词：

green synthesis; Schiff's bases; aromatic aldehydes; aqueous medium; DIELS-ALDER REACTIONS; ORGANIC-REACTIONS; HYDROPHOBIC INTERACTIONS; TRANSITION-STATE; CARBON-MONOXIDE; OXIDATION; WATER; COMPLEXES; CHEMISTRY; CATALYST;

D O I：

10.1080/17518251003716550

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Schiff's bases constitute a class of pharmaceutical and medicinally important molecules. The conventional methods for the synthesis of Schiff's bases require long reaction times and use of organic solvents. We report a novel and eco-friendly condensation reaction method permitting the "green synthesis'' of various Schiff's bases by stirring 1,2-diaminobenzene with various aromatic aldehydes in water as solvent. This method is experimentally simple, clean, high yielding, green, and with reduced reaction times. The product is purified by simple filtration followed by washing with water and drying processes.

引用

页码：217 / 223

页数：7

共 68 条

[1] Aluminium(III)-selective electrode based on a newly synthesized tetradentate Schiff base [J].

Abbaspour, A ;

Esmaeilbeig, AR ;

Jarrahpour, AA ;

Khajeh, B ;

Kia, R .

TALANTA, 2002, 58 (02) :397-403

[2] Polymerization of vinyl monomers via MAO activated iron(II) dichloro complexes bearing bis(imino)pyridine-, quinolinaldimine- and thiophenaldimine-based tridentate nitrogen ligands [J].

Abu-Surrah, Adnan S. ;

Qaroush, Abdussalam K. .

EUROPEAN POLYMER JOURNAL, 2007, 43 (07) :2967-2974

[3]

ADAM FA, 1989, CHEM SCRIPTA, V29, P161

[4] Imines, enamines and oximes [J].

Adams, JP .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (02) :125-139

[5]

AHL E, 2003, SYNTHETIC COMMUN, V33, P989

[6] DESIGN AND SYNTHESIS OF MACROCYCLIC LIGANDS AND THEIR COMPLEXES OF LANTHANIDES AND ACTINIDES [J].

ALEXANDER, V .

CHEMICAL REVIEWS, 1995, 95 (02) :273-342

[7]

Anastas P., 1998, GREEN CHEM THEORY PR

[8]

Anastas P.T., 2000, GREEN CHEM SYNTHESES

[9] Origins, current status, and future challenges of green chemistry [J].

Anastas, PT ;

Kirchhoff, MM .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694

[10] Unification of reaction metrics for green chemistry: Applications to reaction analysis [J].

Andraos, J .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2005, 9 (02) :149-163

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