Remarkably stable chelating bis-N-heterocyclic carbene adducts of phosphorus(I) cations

被引：34

作者：

Binder, Justin F. ^{[1
]}

Swidan, Ala'aeddeen ^{[1
]}

Tang, Martin ^{[1
]}

Nguyen, Jennifer H. ^{[1
]}

Macdonald, Charles L. B. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 36期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

CHEMISTRY; REACTIVITY; IODIDE; ION;

D O I：

10.1039/c5cc00331h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient one-pot synthesis of chelating bis-N-heterocyclic carbene-ligated P-I salts is described. The solid state structures of these remarkably stable phosphamethine cyanine dyes with various N-alkyl groups and counter-anions are reported, and initial reactivity results are discussed.

引用

页码：7741 / 7744

页数：4

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