Palladium-catalyzed carbene insertion into benzyl bromides

被引：94

作者：

Greenman, KL ^{[1
]}

Van Vranken, DL ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

TETRAHEDRON | 2005年 / 61卷 / 26期

基金：

美国国家科学基金会;

关键词：

palladium; carbene; stoichiometric insertion;

D O I：

10.1016/j.tet.2005.03.108

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium can catalyze the insertion of ethyl diazoacetate into benzyl bromides. The key step in the catalytic cycle is the migratory insertion of a carbene, derived from ethyl diazoacetate, into a Pd-C bond. (c) 2005 Elsevier Ltd. All rights reserved.

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收藏

页码：6438 / 6441

页数：4

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