A Cyclometalated Platinum(II) Complex with a Pendent Pyridyl Motif as Solid-State Luminescent Sensor for Acidic Vapors

被引：59
|
作者：
Li, Kai [1 ,2 ]
Chen, Yong [1 ,2 ,3 ]
Lu, Wei [1 ,2 ]
Zhu, Nianyong [1 ,2 ]
Che, Chi-Ming [1 ,2 ,3 ]
机构：
[1] Univ Hong Kong, HKU CAS Joint Lab New Mat, Inst Mol Funct Mat, State Key Lab Synthet Chem, Hong Kong, Hong Kong, Peoples R China
[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[3] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 15期
关键词：
acidic vapor; luminescence; N-heterocyclic carbenes; platinum; sensors; STRUCTURAL BASIS; LIGANDS; BINDING; COMPOUND; CRYSTALS; BEHAVIOR; CARBENE; PROBES; SALTS; IONS;
D O I：
10.1002/chem.201003606
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Acidic light: The reaction of the pincer-type cyclometalated platinum(II) complex [PtCl(η3-N C N)] with an N-heterocyclic carbene (NHC) led to the [Pt(η2-N C N)(NHC)2] + complex with a pendent pyridyl group, which can be protonated by a variety of acidic vapors. This protonation switches the solid-state phosphorescence on (see graphic). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4109 / 4112
页数：4
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