Characteristics of Liquid-Hydrocarbon Yield and Biomarkers in Various Thermal-Evolution Stages: A Simulation Experiment with the Middle Jurassic Source Rocks in the Northern Margin of the Qaidam Basin

被引:0
作者
Chen, Yongxin [1 ,2 ]
Zhang, Xilong [1 ,2 ]
Li, Xiang [3 ]
Liu, Tao [3 ]
Sun, Yaru [3 ]
Zhu, Guotao [3 ]
Ju, Pengfei [4 ]
机构
[1] Chinese Acad Sci, Northwest Inst Ecoenvironm & Resources, Key Lab Petr Resources, Lanzhou 730000, Peoples R China
[2] Xian Shiyou Univ, Xian Key Lab Tight Oil Shale Oil Dev, Xian 710065, Peoples R China
[3] PetroChina, Technol Serv Co, Xinjiang Oilfield Co, Karamay 834000, Peoples R China
[4] PetroChina, Engn Technol Res Inst, Xinjiang Oilfield Co, Karamay 834000, Peoples R China
基金
中国国家自然科学基金;
关键词
biomarkers; liquid hydrocarbons; Middle Jurassic; Qaidam Basin; thermal simulation; ORGANIC-MATTER; PETROLEUM FORMATION; HYDROUS PYROLYSIS; GAS ACCUMULATION; OIL CRACKING; MATURATION; GENERATION; PARAMETERS; SHALES; TIME;
D O I
10.3390/en15207793
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Although there are many studies on the Jurassic source rocks in the northern margin of the Qaidam Basin, the characteristics of biomarkers and products with the same source rock in different evolutionary stages are still not well understood. Such an understanding is essential for accurately estimating oil and gas resources. In order to explore the hydrocarbon-generation potential of high-quality source rocks of the Middle Jurassic and the evolution of liquid hydrocarbons and biomarkers, we carried out simulation research (under hydrous conditions) at various temperatures (250, 300, 350, 400 and 450 degrees C) with the mudstone of the Yu 33 well in the Yuka Sag. The results revealed that the "oil window" of the Middle Jurassic source rocks in the Yuka area was 300 degrees C (simulation temperature, Ro = 0.84%), but this was not the peak of hydrocarbon expulsion, which was gradually reached and stabilized above 350 degrees C. Overall, the concentration of alkanes and aromatics increased with temperature; although the concentration of alkanes was complex in the low evolutionary stages, temperature (simulated maturity) was still the main factor controlling the change in alkanes and aromatics. Among the maturity parameters of biomarkers, the ratio of n-ary sumation tricyclic terpanes/ n-ary sumation hopanes was the most effective parameter for indicating the maturity evolution of the Yuka area, but others were complicated by the increasing temperature. Therefore, when evaluating maturity, the applicability of other parameters needed to be fully considered. The results obtained offer new insights in the research on liquid-hydrocarbon and biomarker evolution of the Middle Jurassic source rocks in the Yuka Sag of the Qaidam Basin.
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页数:14
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