Hierarchical three-dimensional Fe3O4@porous carbon matrix/graphene anodes for high performance lithium ion batteries

被引：62
作者：
Hao, Shiji [1 ]
Zhang, Bowei [2 ]
Wang, Ying [2 ]
Li, Chaojiang [2 ]
Feng, Jianyong [2 ]
Ball, Sarah [3 ]
Srinivasan, Madhavi [1 ,2 ]
Wu, Junsheng [4 ]
Huang, Yizhong [1 ,2 ]
机构：
[1] Nanyang Technol Univ, Energy Res Inst NTU, Singapore 639798, Singapore
[2] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[3] Johnson Matthey Technol Ctr, Reading RG4 9NH, Berks, England
[4] Univ Sci & Technol Beijing, Inst Adv Mat & Technol, Beijing 100083, Peoples R China
来源：
ELECTROCHIMICA ACTA | 2018年 / 260卷
关键词：
Fe3O4; Porous carbon matrix; Graphene; Anode; Lithium ion batteries; METAL-ORGANIC FRAMEWORKS; GRAPHENE OXIDE; FE3O4; NANOPARTICLES; STORAGE CAPACITY; NANOCOMPOSITE; COMPOSITES; CO3O4; MICROSPHERES; FOAM; ELECTRODES;
D O I：
10.1016/j.electacta.2017.12.078
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
In the present paper, the hierarchical three-dimensional Fe3O4@porous carbon matrix (PCM) and Fe3O4@PCM/graphene are synthesized by a facile annealing of Mil-53(Fe) templates. Their electrochemical performances are evaluated as anode materials for lithium ion batteries. In comparison with Fe3O4@PCM, the Fe3O4@PCM/graphene electrode exhibits a much better cycling performance with the reversible capacity high up to 1000 mAh g(-1) after 500 cycles at 1 C. The improved performance can be ascribed to the high conductivity and structure stability provided by the unique graphene based hierarchical three-dimensional nanostructure. (c) 2017 Elsevier Ltd. All rights reserved.
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收藏
页码：965 / 973
页数：9
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