Selective Amine Oxidation Using Nb2O5 Photocatalyst and O2

被引：268

作者：

Furukawa, Shinya ^{[1
]}

Ohno, Yasuhiro ^{[1
]}

Shishido, Tetsuya ^{[1
]}

Teramura, Kentaro ^{[1
]}

Tanaka, Tsunehiro ^{[1
]}

机构：

[1] Kyoto Univ, Dept Mol Engn, Grad Sch Engn, Kyoto 6158510, Japan

来源：

ACS CATALYSIS | 2011年 / 1卷 / 10期

关键词：

amine oxidation; photocatalyst; niobium oxide; selective oxidation; aerobic oxidation; MOLECULAR-OXYGEN; CATALYZED OXIDATION; AEROBIC OXIDATION; SECONDARY-AMINES; VISIBLE-LIGHT; IMINES; PHOTOOXIDATION; MECHANISM; ALCOHOLS; OXIDE;

D O I：

10.1021/cs200318n

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Niobium oxide (Nb2O5) can function as a photocatalyst for selective oxidation of benzylamine rather than other semiconductor metal, oxides such as TiO2, ZnO, and WO3. Various amines including primary, secondary, and cyclic amines are also photo catalytically converted to corresponding imines in excellent yields by using Nb2O5 in an atmospheric pressure of O-2. Nb2O5 exhibits a catalytic activity with high selectivity even under visible light (lambda > 390 nm) irradiation, although Nb2O5 does not absorb visible light.

引用

页码：1150 / 1153

页数：4

共 50 条

[1] Solvent-free aerobic alcohol oxidation using Cu/Nb2O5: Green and highly selective photocatalytic system
Furukawa, Shinya
Tamura, Ayaka
Shishido, Tetsuya
Teramura, Kentaro
Tanaka, Tsunehiro
APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 110 : 216 - 220
[2] Selective Aerobic Oxidation of Primary Alcohols to Aldehydes over Nb2O5 Photocatalyst with Visible Light
Furukawa, Shinya
Shishido, Tetsuya
Teramura, Kentaro
Tanaka, Tsunehiro
CHEMPHYSCHEM, 2014, 15 (13) : 2665 - 2667
[3] Selective Photocatalytic Oxidation of Benzyl Amine by O2 into N-benzylidenebenzylamine on TiO2 Using Visible Light
Higashimoto, Shinya
Hatada, Yoshiaki
Ishikawa, Ryo
Azuma, Masashi
Sakata, Yoshihisa
Kobayashi, Hisayoshi
CURRENT ORGANIC CHEMISTRY, 2013, 17 (21) : 2374 - 2381
[4] Anchoring dye onto 1D Nb2O5 in cooperation with TEMPO for the selective photocatalytic aerobic oxidation of amines
Ma, Xiaoming
Li, Xia
Zhou, Jun
Wang, Yuexin
Lang, Xianjun
CHEMICAL ENGINEERING JOURNAL, 2021, 426
[5] Morphological Evolution of Nb2O5 in a Solvothermal Reaction: From Nb2O5 Grains to Nb2O5 Nanorods and Hexagonal Nb2O5 Nanoplatelets
Hu Weibing
Liu Zuli
Tian Dating
Zhang Shengmin
Zhao Yimin
Yao Kailun
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2009, 24 (02): : 245 - 248
[6] Underwater superoleophobicity of Nb2O5 photocatalyst surface
Nishimoto, Shunsuke
Takiguchi, Takahiro
Kameshima, Yoshikazu
Miyake, Michihiro
CHEMICAL PHYSICS LETTERS, 2019, 726 : 34 - 38
[7] Visible-Light-Driven Furfural Oxidation over CuOx/Nb2O5
Ren, Puning
Zhou, Yue
Su, Kaiyi
Sun, Lulu
Luo, Nengchao
Wang, Feng
CHEMISTRY-AN ASIAN JOURNAL, 2023, 18 (22)
[8] Photocatalytic Selective Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran over Nb2O5 under Visible Light
Zhang, Huili
Wu, Qi
Guo, Cong
Wu, Ying
Wu, Tinghua
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (04): : 3517 - 3523
[9] Cu/Nb2O5, Fe/Nb2O5 and Cu-Fe/Nb2O5 applied in salicylic acid degradation: Parameters studies and photocatalytic activity
Fuziki, Maria E. K.
Abreu, Eduardo
Napoli, Jose S.
Nunes, Sabrina C.
Brackmann, Rodrigo
Machado, Tauani C. S.
Semianko, Betina C.
Lenzi, Giane G.
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2022, 57 (09): : 797 - 812
[10] Visible-Light-Driven Selective Oxidation of Toluene into Benzaldehyde over Nitrogen-Modified Nb2O5 Nanomeshes
Su, Kaiyi
Liu, Huifang
Zeng, Bin
Zhang, Zhixin
Luo, Nengchao
Huang, Zhipeng
Gao, Zhuyan
Wang, Feng
ACS CATALYSIS, 2020, 10 (02): : 1324 - 1333

← 1 2 3 4 5 →