Study on Mn(III)-Salen and catalysis for styrene oxidation

被引：14

作者：

Zhang, Zhang ^{[1
]}

Zhi-Wu, Ye ^{[1
]}

Min, Zhang ^{[1
]}

Fan ChunYan ^{[1
]}

机构：

[1] Shanghai Univ, Dept Chem Engn & Technol, Shanghai 201800, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2008年 / 38卷 / 04期

关键词：

benzaldehyde; catalytic selectivity; Mn( III)-Salen; styrene oxidation;

D O I：

10.1080/15533170802132014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this paper, three Mn(III)-Salen complexes are synthesized and their catalytic activity for styrene oxidation were studied. Four Shifft-basa are prepared by condensation of salicylaldehyde or its derivatives with diamine, then chelated with Mn and formed into Mn(III)-Salen complexes. Their chemical structures are characterized by IR, UV, etc. Furthermore, the catalytic activities of the Salen compounds for styrene oxidation with oxygen are primarily explored. The experiments show that among them, Mn(III)-Salen-2 is the most excellent catalyst for styrene oxidation with high conversion of styrene (77.1%) and selectivity of benzaldehyde (90.4%).

引用

页码：352 / 355

页数：4

共 6 条

[1] Synthesis of enantiopure 3-chlorostyrene oxide via an asymmetric epoxidation-hydrolytic kinetic resolution sequence
Brandes, BD
Jacobsen, EN
[J]. TETRAHEDRON-ASYMMETRY, 1997, 8 (23) : 3927 - 3933
[2] DIAN C, 1987, INORG CHEM, V26, P1026
[3] Functional mimics of superoxide dismutase enzymes as therapeutic agents
Riley, DP
[J]. CHEMICAL REVIEWS, 1999, 99 (09) : 2573 - 2587
[4] Manganese(III) complexes with porphyrins and related compounds as catalytic scavengers of superoxide
Spasojevic, I
Batinic-Haberle, I
[J]. INORGANICA CHIMICA ACTA, 2001, 317 (1-2) : 230 - 242
[5] Oxidation catalysis of a manganese(III)porphyrin intercalated in layered double hydroxide clays
Tong, ZW
Shichi, T
Takagi, K
[J]. MATERIALS LETTERS, 2003, 57 (15) : 2258 - 2261
[6] XINBIN C, 2000, ACTA CHIM SINICA, V58, P971

← 1 →