Identification of intrinsic hydrogen impurities in ZnO with 1H solid-state nuclear magnetic resonance spectroscopy

被引：17

作者：

Wang, Meng ^{[1
]}

Yu, Guiyun ^{[1
,2
]}

Ji, Wenxu ^{[1
]}

Li, Lei ^{[1
]}

Ding, Weiping ^{[1
]}

Peng, Luming ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem MOE, Nanjing 210093, Jiangsu, Peoples R China

[2] Yancheng Inst Technol, Sch Chem & Biol Engn, Yancheng 224051, Peoples R China

来源：

CHEMICAL PHYSICS LETTERS | 2015年 / 627卷

基金：

中国国家自然科学基金;

关键词：

LAYERED DOUBLE HYDROXIDES; ZINC-OXIDE; MAS-NMR; NEUTRON-DIFFRACTION; ZEOLITE HY; BONDS; EPSILON-ZN(OH)(2);

D O I：

10.1016/j.cplett.2015.03.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

H-1 solid-state nuclear magnetic resonance (NMR) spectroscopy was used to study intrinsic hydrogen (H) impurities in zinc oxide (ZnO), which play a key role in its n-type conductivity. Two H-1 signals were resolved, and assigned for the first time, to interstitial H species (H-i) and H species substituting for oxygen ions (H-O), with the help from the model compound zinc hydroxide (epsilon-Zn(OH)(2)) and H-1 -> O-17 double resonance NMR spectroscopy. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：7 / 12

页数：6

共 50 条

[41] Genotype evaluation of cowpea seeds (Vigna unguiculata) using 1H qNMR combined with exploratory tools and solid-state NMR
Alves Filho, Elenilson G.
Silva, Lorena M. A.
Teofilo, Elizita M.
Larsen, Flemming H.
de Brito, Edy S.
FOOD RESEARCH INTERNATIONAL, 2017, 91 : 140 - 147
[42] High-resolution solid-state 27Al and 29Si nuclear magnetic resonance study of natural montmorillonite in China
郭九皋
李丽云
袁汉珍
杨年华
王德强
陈丰
Chinese Science Bulletin, 1995, (12) : 1007 - 1011
[43] Solid-State 31P Nuclear Magnetic Resonance Study of Interlayer Hydroxide Surfaces of Kaolinite Probed with an Interlayer Triethylphosphine Oxide Monolayer
Machida, Shingo
Sohmiya, Minoru
Ide, Yusuke
Sugahara, Yoshiyuki
LANGMUIR, 2018, 34 (43) : 12694 - 12701
[44] Nanostructure of CaO-(Na2O)-Al2O3-SiO2-H2O Gels Revealed by Multinuclear Solid-State Magic Angle Spinning and Multiple Quantum Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy
Walkley, Brant
Page, Samuel J.
Rees, Gregory J.
Provis, John L.
Hanna, John V.
JOURNAL OF PHYSICAL CHEMISTRY C, 2020, 124 (02) : 1681 - 1694
[45] Phosphorus-31 and vanadium-51 solid-state nuclear magnetic resonance spectroscopy of β-vanadyl phosphate - Effects of homo- and heteronuclear spin-spin, electrostatic, and paramagnetic interactions
Eichele, Klaus
Grimmer, Arnd-Ruediger
CANADIAN JOURNAL OF CHEMISTRY, 2011, 89 (07) : 870 - 884
[46] Quantitative analysis of 14N quadrupolar coupling using 1H detected 14N solid-state NMR
Jarvis, James A.
Concistre, Maria
Haies, Ibraheem M.
Bounds, Richard W.
Kuprov, Ilya
Carravetta, Marina
Williamson, Philip T. F.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2019, 21 (11) : 5941 - 5949
[47] Structural investigations of perlite and expanded perlite using 1H, 27Al and 29Si solid-state NMR
Zujovic, Zoran
Wheelwright, Walt V. K.
Kilmartin, Paul A.
Hanna, John V.
Cooney, Ralph P.
CERAMICS INTERNATIONAL, 2018, 44 (03) : 2952 - 2958
[48] Advanced solid-state 1H/31P NMR characterization of pyrophosphate-doped calcium phosphate cements for biomedical applications: The structural role of pyrophosphate
Yu, Yang
Guo, Hua
Pujari-Palmer, Michael
Stevensson, Baltzar
Grins, Jekabs
Engqvist, Hakan
Eden, Mattias
CERAMICS INTERNATIONAL, 2019, 45 (16) : 20642 - 20655
[49] Solid-state 31P and 1H chemical MR micro-imaging of hard tissues and biomaterials with magic angle spinning at very high magnetic field
Yon, Maxime
Sarou-Kanian, Vincent
Scheler, Ulrich
Bouler, Jean-Michel
Bujoli, Bruno
Massiot, Dominique
Fayon, Franck
SCIENTIFIC REPORTS, 2017, 7
[50] Effects of varying water adsorption on a Cu3(BTC)2 metal-organic framework (MOF) as studied by 1H and 13C solid-state NMR spectroscopy
Gul-E-Noor, Farhana
Jee, Bettina
Poeppl, Andreas
Hartmann, Martin
Himsl, Dieter
Bertmer, Marko
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (17) : 7783 - 7788

← 1 2 3 4 5 →