Identification of intrinsic hydrogen impurities in ZnO with 1H solid-state nuclear magnetic resonance spectroscopy

被引：17
|
作者：
Wang, Meng [1 ]
Yu, Guiyun [1 ,2 ]
Ji, Wenxu [1 ]
Li, Lei [1 ]
Ding, Weiping [1 ]
Peng, Luming [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem MOE, Nanjing 210093, Jiangsu, Peoples R China
[2] Yancheng Inst Technol, Sch Chem & Biol Engn, Yancheng 224051, Peoples R China
来源：
CHEMICAL PHYSICS LETTERS | 2015年 / 627卷
基金：
中国国家自然科学基金;
关键词：
LAYERED DOUBLE HYDROXIDES; ZINC-OXIDE; MAS-NMR; NEUTRON-DIFFRACTION; ZEOLITE HY; BONDS; EPSILON-ZN(OH)(2);
D O I：
10.1016/j.cplett.2015.03.024
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
H-1 solid-state nuclear magnetic resonance (NMR) spectroscopy was used to study intrinsic hydrogen (H) impurities in zinc oxide (ZnO), which play a key role in its n-type conductivity. Two H-1 signals were resolved, and assigned for the first time, to interstitial H species (H-i) and H species substituting for oxygen ions (H-O), with the help from the model compound zinc hydroxide (epsilon-Zn(OH)(2)) and H-1 -> O-17 double resonance NMR spectroscopy. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：7 / 12
页数：6
相关论文
共 50 条
  • [1] Probing hydrogen in ZnO nanorods using solid-state 1H nuclear magnetic resonance
    Wang, Li-Qiong
    Exarhos, Gregory J.
    Windisch, Charles F., Jr.
    Yao, Chunhua
    Pederson, Larry R.
    Zhou, Xiao-Dong
    APPLIED PHYSICS LETTERS, 2007, 90 (17)
  • [2] Proton dynamics in ZnO nanorods quantified by in situ solid-state 1H nuclear magnetic resonance spectroscopy
    Wang, Li-Qiong
    Zhou, Xiao-Dong
    Exarhos, Gregory J.
    Pederson, Larry R.
    Wang, Chongmin
    Windisch, Charles F., Jr.
    APPLIED PHYSICS LETTERS, 2007, 91 (17)
  • [3] Solid-state nuclear magnetic resonance spectroscopy of cements
    Walkley, B.
    Provis, J. L.
    MATERIALS TODAY ADVANCES, 2019, 1
  • [4] Cellular solid-state nuclear magnetic resonance spectroscopy
    Renault, Marie
    Tommassen-van Boxtel, Ria
    Bos, Martine P.
    Post, Jan Andries
    Tommassen, Jan
    Baldus, Marc
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2012, 109 (13) : 4863 - 4868
  • [5] 1H nuclear magnetic resonance study of distinct interstitial hydrogen dynamics in ZnO
    Park, Jun Kue
    Lee, Kyu Won
    Lee, Cheol Eui
    SOLID STATE COMMUNICATIONS, 2013, 165 : 19 - 21
  • [6] Solid-state nuclear magnetic resonance spectroscopy - Pharmaceutical applications
    Tishmack, PA
    Bugay, DE
    Byrn, SR
    JOURNAL OF PHARMACEUTICAL SCIENCES, 2003, 92 (03) : 441 - 474
  • [7] SOLID-STATE NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY OF MINERALS
    KIRKPATRICK, RJ
    SMITH, KA
    SCHRAMM, S
    TURNER, G
    YANG, WH
    ANNUAL REVIEW OF EARTH AND PLANETARY SCIENCES, 1985, 13 : 29 - 47
  • [8] SOLID-STATE NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY OF MINERALS.
    Kirkpatrick, R.James
    Smith, Karen Ann
    Schramm, Suzanne
    Turner, Gary
    Yang, Wang-Hong
    Annual Review of Earth and Planetary Sciences, 1985, 13 : 29 - 47
  • [9] Spectrometer for stochastic solid-state nuclear magnetic resonance spectroscopy
    Hirsch, O
    Scheler, G
    Jäger, C
    REVIEW OF SCIENTIFIC INSTRUMENTS, 2001, 72 (03): : 1734 - 1741
  • [10] Recent Advances in Solid-State Nuclear Magnetic Resonance Spectroscopy
    Ashbrook, Sharon E.
    Griffin, John M.
    Johnston, Karen E.
    ANNUAL REVIEW OF ANALYTICAL CHEMISTRY, VOL 11, 2018, 11 : 485 - 508
12345