Identification of intrinsic hydrogen impurities in ZnO with 1H solid-state nuclear magnetic resonance spectroscopy

被引：17
|
作者：
Wang, Meng [1 ]
Yu, Guiyun [1 ,2 ]
Ji, Wenxu [1 ]
Li, Lei [1 ]
Ding, Weiping [1 ]
Peng, Luming [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem MOE, Nanjing 210093, Jiangsu, Peoples R China
[2] Yancheng Inst Technol, Sch Chem & Biol Engn, Yancheng 224051, Peoples R China
来源：
CHEMICAL PHYSICS LETTERS | 2015年 / 627卷
基金：
中国国家自然科学基金;
关键词：
LAYERED DOUBLE HYDROXIDES; ZINC-OXIDE; MAS-NMR; NEUTRON-DIFFRACTION; ZEOLITE HY; BONDS; EPSILON-ZN(OH)(2);
D O I：
10.1016/j.cplett.2015.03.024
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
H-1 solid-state nuclear magnetic resonance (NMR) spectroscopy was used to study intrinsic hydrogen (H) impurities in zinc oxide (ZnO), which play a key role in its n-type conductivity. Two H-1 signals were resolved, and assigned for the first time, to interstitial H species (H-i) and H species substituting for oxygen ions (H-O), with the help from the model compound zinc hydroxide (epsilon-Zn(OH)(2)) and H-1 -> O-17 double resonance NMR spectroscopy. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：7 / 12
页数：6
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